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N,N′-(1R,2R)-(-)-1,2-cyclohexanediylbis[2-hydroxy-7,7-dimethyl-bicyclo[2.2.1]heptane-1-methanesulfonamide]_Molecular_structure_CAS_)
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N,N′-(1R,2R)-(-)-1,2-cyclohexanediylbis[2-hydroxy-7,7-dimethyl-bicyclo[2.2.1]heptane-1-methanesulfonamide]

Catalog No. 673315 Name Sigma Aldrich
CAS Number Website http://www.sigmaaldrich.com
M. F. C26H46N2O6S2 Telephone 1-800-521-8956
M. W. 546.78324 Fax
Purity 97% Email
Storage Chembase ID: 141110

SYNONYMS

Title
N,N′-(1R,2R)-(-)-1,2-环己二基双[2-羟基-7,7-二甲基-二环[2.2.1]庚烷-1-甲烷磺酰胺]
IUPAC name
1-{2-hydroxy-7,7-dimethylbicyclo[2.2.1]heptan-1-yl}-N-[(1R,2R)-2-({2-hydroxy-7,7-dimethylbicyclo[2.2.1]heptan-1-yl}methanesulfonamido)cyclohexyl]methanesulfonamide
IUPAC Traditional name
1-{2-hydroxy-7,7-dimethylbicyclo[2.2.1]heptan-1-yl}-N-[(1R,2R)-2-({2-hydroxy-7,7-dimethylbicyclo[2.2.1]heptan-1-yl}methanesulfonamido)cyclohexyl]methanesulfonamide

DATABASE IDS

PubChem SID 24885156

PROPERTIES

Empirical Formula (Hill Notation) C26H46N2O6S2
Purity 97%
Melting Point 194-198 °C
Optical Rotation [α]20/D -36°, c = 1 in chloroform
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26
German water hazard class 3

DETAILS

Description (English)
Application
Ligand employed in the titanium-catalyzed vinylation of ketones and enones with vinylzinc reagents.1
Packaging
250 mg in glass bottle
Description (简体中文)
Application
在乙烯基锌试剂作用下进行钛催化的酮和烯酮乙烯化时用到的配体。1
包装
250 mg in glass bottle

REFERENCES