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Diiodo(bis(diphenylphosphino)ethane)cobalt(II)_Molecular_structure_CAS_34775-39-8)
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Diiodo(bis(diphenylphosphino)ethane)cobalt(II)

Catalog No. 685631 Name Sigma Aldrich
CAS Number 34775-39-8 Website http://www.sigmaaldrich.com
M. F. C26H24CoI2P2 Telephone 1-800-521-8956
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Storage Chembase ID: 141091

SYNONYMS

Title
二碘(双(二苯基膦)乙烷)钴(II)
IUPAC name
[2-(diphenylphosphanyl)ethyl]diphenylphosphane; diiodocobalt
IUPAC Traditional name
diiodocobalt; diphos
Synonyms
[1,2-乙烷二基双[二苯基膦-Κ, P]]二碘-钴
[1,2-Ethanediylbis[diphenylphosphine-Κ, P]]diiodo-cobalt

DATABASE IDS

MDL Number MFCD11045354
CAS Number 34775-39-8

PROPERTIES

Linear Formula CoI2(P(C6H5)2C2H4P(C6H5)2)
Melting Point >300 °C
MSDS Link Download

DETAILS

Description (English)
Application
Catalyst for the mild coupling of thiols with aryl and heteroaryl iodides to give sulfides.4
Catalyzes the cyclization of 2-iodobenzoates with aldehydes to give phthalides (isobenzofuranones).2
Catalyst for:
• Reductive coupling reactions1
• Cyclization reactions2
• Reductive [3 + 2] cycloaddition reactions3
• Aryl-sulfur bond formation4
• Dimerization reactions5
Packaging
1 g in glass bottle
250 mg in glass bottle
Description (简体中文)
Application
用于催化 2-碘代苯甲酸酯与醛环化生成苯酞(异苯并呋喃酮)。2
用于硫醇类与芳基和杂芳基碘经温和偶联反应生成硫化物的催化剂。4
Catalyst for:
• Reductive coupling reactions1
• Cyclization reactions2
• Reductive [3 + 2] cycloaddition reactions3
• Aryl-sulfur bond formation4
• Dimerization reactions5
包装
1 g in glass bottle
250 mg in glass bottle

REFERENCES