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Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer_Molecular_structure_CAS_12257-42-0)
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Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer

Catalog No. 683167 Name Sigma Aldrich
CAS Number 12257-42-0 Website http://www.sigmaaldrich.com
M. F. C14H16Cl2Rh2 Telephone 1-800-521-8956
M. W. 460.99384 Fax
Purity Email
Storage Chembase ID: 139982

SYNONYMS

Title
氯降冰片二烯铑二聚体
IUPAC name
bis((1s,4s)-bicyclo[2.2.1]hepta-2,5-diene); bis(chlororhodium)
IUPAC Traditional name
bis((1s,4s)-bicyclo[2.2.1]hepta-2,5-diene); bis(chlororhodium)
Synonyms
[Rh(nbd)Cl]2
二氯化二铑(双降冰片二烯)
降冰片二烯氯化铑二聚体
Rhodium(I) chloride 2,5-Norbornadiene complex dimer
2,5-Norbornadiene-rhodium(I) chloride dimer
Chloro(2,5-norbornadiene)rhodium(I) dimer
氯化降冰片二烯铑二聚物

DATABASE IDS

MDL Number MFCD00198060
EC Number 235-510-4
CAS Number 12257-42-0

PROPERTIES

Empirical Formula (Hill Notation) C14H16Cl2Rh2
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Application
Catalyst for valence isomerization and N-heterocyclization; incombination with phosphorus ligands are catalysts for hydrogenationof many functional groups and hydroformylation; withchiral ligands are catalysts for asymmetric hydrogenation
Umicore Precatalysts for Asymmetric and Cross-Coupling CatalysisHydrosilylation Catalysts
Packaging
2 g in glass bottle
500 mg in glass bottle
Legal Information
A product of Umicore.
Description (简体中文)
Application
Catalyst for valence isomerization and N-heterocyclization; incombination with phosphorus ligands are catalysts for hydrogenationof many functional groups and hydroformylation; withchiral ligands are catalysts for asymmetric hydrogenation
Umicore Precatalysts for Asymmetric and Cross-Coupling CatalysisHydrosilylation Catalysts
包装
2 g in glass bottle
500 mg in glass bottle
Legal Information
Umicore 产品。

REFERENCES