(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer

• Catalog No.: 685062
• CAS Number: 12148-71-9
• M. F.: C18H30Ir2O2
• M. W.: 662.8636

SYNONYMS

• Title: 甲氧基(环辛二烯)合铱二聚体
• IUPAC name: bis(cycloocta-1,5-diene); dimethyl-2,4-dioxa-1,3-diiridabicyclo[1.1.0]butane-2,4-diium-1,3-diuide
• IUPAC Traditional name: bis(1,5-cyclooctadiene); dimethyl-2,4-dioxa-1,3-diiridabicyclo[1.1.0]butane-2,4-diium-1,3-diuide
• Synonyms: 二(1,5-环辛二烯)二-Μ-甲氧基二铱(I); Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I); [Ir(OMe)(1,5-cod)]2

DATABASE IDS

• MDL Number: MFCD08459360
• CAS Number: 12148-71-9

PROPERTIES

• Linear Formula: [Ir(OCH3)(C8H12)]2
• Melting Point: 154-179 °C (D)
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1 g in glass bottle
250 mg in glass bottle
Application
Catalyst for:
• Preparation of heteroaryl fused indole ring systems as inhibitors of HCV NS5B polymerase1
• Borylation/Suzuki-Miyaura coupling2
• Metalation-Suzuki cross-coupling procedure for the synthesis of biaryls and heterobiaryls3
• Tetraborylation reactions4
• Highly regio- and enantioselective asymmetric hydroboration5
• Ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation6
Citation
A powerful C-H activation catalyst to prepare phenols from arenes7

Description (简体中文)

包装
1 g in glass bottle
250 mg in glass bottle
Application
Catalyst for:
• Preparation of heteroaryl fused indole ring systems as inhibitors of HCV NS5B polymerase1
• Borylation/Suzuki-Miyaura coupling2
• Metalation-Suzuki cross-coupling procedure for the synthesis of biaryls and heterobiaryls3
• Tetraborylation reactions4
• Highly regio- and enantioselective asymmetric hydroboration5
• Ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation6
Citation
一种强效的 C-H 键活化催化剂，可用于由芳烃制备酚。7