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(S)-Ru(OAc)2(BINAP)_Molecular_structure_CAS_261948-85-0)
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(S)-Ru(OAc)2(BINAP)

Catalog No. 693189 Name Sigma Aldrich
CAS Number 261948-85-0 Website http://www.sigmaaldrich.com
M. F. C48H38O4P2Ru Telephone 1-800-521-8956
M. W. 841.830442 Fax
Purity Email
Storage Chembase ID: 141016

SYNONYMS

IUPAC name
{1-[2-(diphenylphosphanyl)naphthalen-1-yl]naphthalen-2-yl}diphenylphosphane (acetyloxy)ruthenio acetate
IUPAC Traditional name
binap (acetyloxy)ruthenio acetate
Synonyms
二乙酸根[(S)-(+)-2,2′-二(二苯基膦基)-1,1′-联萘基]钌(II)
Diacetato[(S)-(-)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]ruthenium(II)

DATABASE IDS

MDL Number MFCD09753020
CAS Number 261948-85-0

PROPERTIES

Empirical Formula (Hill Notation) C48H38O4P2Ru
MSDS Link Download
Storage Temperature 2-8°C

DETAILS

Description (English)
Packaging
100, 500 mg in glass bottle
Legal Information
Sold in collaboration with Takasago for research purposes only.
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst for:
• Synthesis of zaragozic acid D and formal syntheses of zaragozic acids A and C
• Enantioselective synthesis of the spirocyclic C-arylglycopyranoside (+)-papulacandin D via palladium-catalyzed, organosilanolate-based cross-coupling reaction and a Lewis-base catalyzed, enantioselective allylation reaction
• Asymmetric hydrogenation of 2-formyl-1-methylene-1,2,3,4-tetrahydroisoquinoline
• Asymmetric reduction of (nitro)(phenyl)propene
• Asymmetric synthesis of chiral d-lactones via hydrogenation
• Asymmetric hydrogenation of bis(diphenylphosphinoyl)butadiene
Description (简体中文)
包装
100, 500 mg in glass bottle
Legal Information
与 Takasago 合作销售,仅用于研究目的。日本注册号 1800526
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst for:
• Synthesis of zaragozic acid D and formal syntheses of zaragozic acids A and C
• Enantioselective synthesis of the spirocyclic C-arylglycopyranoside (+)-papulacandin D via palladium-catalyzed, organosilanolate-based cross-coupling reaction and a Lewis-base catalyzed, enantioselective allylation reaction
• Asymmetric hydrogenation of 2-formyl-1-methylene-1,2,3,4-tetrahydroisoquinoline
• Asymmetric reduction of (nitro)(phenyl)propene
• Asymmetric synthesis of chiral d-lactones via hydrogenation
• Asymmetric hydrogenation of bis(diphenylphosphinoyl)butadiene

REFERENCES