RuCl2[(S)-(DM-BINAP)][(S)-DAIPEN]

• Catalog No.: 693227
• CAS Number: 220114-01-2
• M. F.: C71H72Cl2N2O2P2Ru
• M. W.: 1219.267102

SYNONYMS

• IUPAC name: (4S)-1,1-dichloro-12',12',14',14'-tetrakis(3,5-dimethylphenyl)-3,3-bis(4-methoxyphenyl)-4-(propan-2-yl)-2,5-diaza-12'λ^5,14'λ^5-diphospha-1-ruthenaspiro[cyclopentane-1,13'-pentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosane]-1'(15'),2',4',6',8',10',16',18',20',22'-decaene
• IUPAC Traditional name: (4S)-1,1-dichloro-12',12',14',14'-tetrakis(3,5-dimethylphenyl)-4-isopropyl-3,3-bis(4-methoxyphenyl)-2,5-diaza-12'λ^5,14'λ^5-diphospha-1-ruthenaspiro[cyclopentane-1,13'-pentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosane]-1'(15'),2',4',6',8',10',16',18',20',22'-decaene
• Synonyms: Dichloro[(S)-(-)-2,2′-bis[di(3,5-xylyl)phosphino]-1,1′-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II); 二氯[(S)-(-)-2,2′-二[二(3,5-二甲苯基)膦基]-1,1′-联萘基][(2S)-(+)-1,1-二(4-甲氧苯基)-3-甲基-1,2-丁二胺]钌(II)

DATABASE IDS

• CAS Number: 220114-01-2

PROPERTIES

• Empirical Formula (Hill Notation): C71H74Cl2N2O2P2Ru
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26
• Storage Temperature: 2-8°C
• German water hazard class: 3

DETAILS

Description (English)

Packaging
50, 100 mg in glass bottle
Legal Information
Sold in collaboration with Takasago for research purposes only. JP Registration No. 2041996, 2731377, 2935453 JP Appllication No. 19970359654
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst for:
• Preparation of cyclometalated ruthenium 1,1-dianisyl-2-isopropyl-1,2-ethylenediamine complexes via asymmetric hydrogenation of ketones
• Enantioselective hydrogenation of an α-alkoxy substituted ketone with chiral ruthenium (phosphinoferrocenyl)oxazoline complexes
• Nonclassical asymmeteric hydrogen transfer between alcohols and carbonyl compounds
• Asymmetric hydrogenation of amino and heteroaromatic ketones
• Pharmacologically active substituted oxazolidinone used as NPC1L1 ligand for inhibition of cholesterol absorption

Description (简体中文)

包装
50, 100 mg in glass bottle
Legal Information
与 Takasago 合作销售，仅用于研究目的。日本注册号 041996, 2731377, 2935453，日本申请号19970359654
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst for:
• Preparation of cyclometalated ruthenium 1,1-dianisyl-2-isopropyl-1,2-ethylenediamine complexes via asymmetric hydrogenation of ketones
• Enantioselective hydrogenation of an α-alkoxy substituted ketone with chiral ruthenium (phosphinoferrocenyl)oxazoline complexes
• Nonclassical asymmeteric hydrogen transfer between alcohols and carbonyl compounds
• Asymmetric hydrogenation of amino and heteroaromatic ketones
• Pharmacologically active substituted oxazolidinone used as NPC1L1 ligand for inhibition of cholesterol absorption