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(5S)-(-)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone dichloroacetic acid_Molecular_structure_CAS_345358-20-5)
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(5S)-(-)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone dichloroacetic acid

Catalog No. 663085 Name Sigma Aldrich
CAS Number 345358-20-5 Website http://www.sigmaaldrich.com
M. F. C15H20Cl2N2O3 Telephone 1-800-521-8956
M. W. 347.2369 Fax
Purity 97% Email
Storage Chembase ID: 140988

SYNONYMS

Title
(5S)-(-)-2,2,3-三甲基-5-苄基-4-咪唑啉酮二氯乙酸
IUPAC name
(5S)-5-benzyl-2,2,3-trimethylimidazolidin-4-one; 2,2-dichloroacetic acid
IUPAC Traditional name
(5S)-5-benzyl-2,2,3-trimethylimidazolidin-4-one; dichloroacetic acid
Synonyms
(5S)-2,2,3-三甲基-5-苯甲基-4-咪唑啉酮二氯乙酸
(5S)-2,2,3-Trimethyl-5-phenylmethyl-4-imidazolidinone dichloroacetic acid

DATABASE IDS

MDL Number MFCD08276841
PubChem SID 24884183
CAS Number 345358-20-5

PROPERTIES

Empirical Formula (Hill Notation) C15H20Cl2N2O3
Purity 97%
Melting Point 122-126 °C
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H315-H318-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P280-P305 + P351 + P338
Risk Statements 37/38-41
Safety Statements 26-39
German water hazard class 3

DETAILS

Description (English)
Application
Utilized in the first example of organocatalytic enantioselective α-fluorination of aldehydes.1
Packaging
2 g in glass bottle
500 mg in glass bottle
Legal Information
U.S. Pat. 6,369,243 and related patents apply. For research purposes only.
Protocols & Applications
Metal-free Asymmetric Catalysis using Macmillan Imidazolidinone Organocatalysts
Description (简体中文)
Application
用于首例有机催化的醛对映选择性 α-氟化。1
包装
2 g in glass bottle
500 mg in glass bottle
Legal Information
适用美国专利6,369,243 和相关专利。仅供研究使用。
Protocols & Applications
Metal-free Asymmetric Catalysis using Macmillan Imidazolidinone Organocatalysts

REFERENCES