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(5R)-(+)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride_Molecular_structure_CAS_323196-43-6)
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(5R)-(+)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride

Catalog No. 663069 Name Sigma Aldrich
CAS Number 323196-43-6 Website http://www.sigmaaldrich.com
M. F. C13H19ClN2O Telephone 1-800-521-8956
M. W. 254.75576 Fax
Purity 97% Email
Storage Chembase ID: 140985

SYNONYMS

Title
(5R)-(+)-2,2,3-三甲基-5-苄基-4-咪唑啉酮 单盐酸盐
IUPAC name
(5R)-5-benzyl-2,2,3-trimethylimidazolidin-4-one hydrochloride
IUPAC Traditional name
(5R)-5-benzyl-2,2,3-trimethylimidazolidin-4-one hydrochloride
Synonyms
(5R)-2,2,3-Trimethyl-5-phenylmethyl-4-imidazolidinone monohydrochloride
(5R)-2,2,3-三甲基-5-苯甲基-4-咪唑啉酮 单盐酸盐

DATABASE IDS

MDL Number MFCD08276839
CAS Number 323196-43-6
PubChem SID 24884181

PROPERTIES

Empirical Formula (Hill Notation) C13H19ClN2O
Purity 97%
Melting Point 157-161 °C
Optical Rotation [α]20/D +67°, c = 1 in H2O
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Application
Used in first highly enantioselective organocatalytic Diels-Alder reaction1 and 1,3-dipolar addition.2
Packaging
2 g in glass bottle
500 mg in glass bottle
Legal Information
U.S. Pat. 6,369,243 and related patents apply. For research purposes only.
Protocols & Applications
Metal-free Asymmetric Catalysis using Macmillan Imidazolidinone Organocatalysts
Description (简体中文)
Application
用于首例高对映选择性有机催化 Diels-Alder 反应1和 1,3-偶极加成。2
包装
2 g in glass bottle
500 mg in glass bottle
Legal Information
适用美国专利6,369,243 和相关专利。仅供研究使用。
Protocols & Applications
Metal-free Asymmetric Catalysis using Macmillan Imidazolidinone Organocatalysts

REFERENCES