Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](3-methyl-2-butenylidene) (tricyclohexylphosphine)ruthenium(II)

• Catalog No.: 682365
• CAS Number: 253688-91-4
• M. F.: C44H67Cl2N2PRu
• M. W.: 826.965941

SYNONYMS

• Title: 二氯[1,3-双(2,4,6-三甲基苯基)-2-咪唑烷亚基](3-甲基-2-亚丁烯基)(三环己基膦)钌(II)
• IUPAC name: [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichloro(3-methylbut-2-en-1-ylidene)ruthenium; tricyclohexylphosphane
• IUPAC Traditional name: [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichloro(3-methylbut-2-en-1-ylidene)ruthenium; tricyclohexylphosphine
• Synonyms: [SIMes]dichloro(3-methyl-2-butenylidene)(tricyclohexylphosphine)Ru(II); Isopentenylidene(1,3-dimesitylimidazolidin-2-ylidene) (tricyclohexylphosphine)ruthenium(II) dichloride; 异亚戊烯基(1,3-双(2,4,6-三甲基苯基)-咪唑烷-2-亚基)(三环己基膦)二氯化钌(II); [SIMes]二氯(3-甲基-2-亚丁烯基)(三环己基膦)Ru(II)

DATABASE IDS

• CAS Number: 253688-91-4
• PubChem SID: 24885711
• MDL Number: MFCD09265165

PROPERTIES

• Empirical Formula (Hill Notation): C44H67Cl2N2PRu
• GHS Signal Word: Warning
• GHS Hazard statements: H228
• European Hazard Symbols: Flammable (F)
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• GHS Precautionary statements: P210
• Risk Statements: 11
• Storage Temperature: 2-8°C
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
NO BULK ORDERS
Packaging
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
Sale of this product conveys to the buyer a limited-use research license. For full details of this license please see sigma-aldrich.com/materialicense. For questions, please contact us at aldrich@sial.com or Materia at info@materia-inc.com.
Application
Metathesis: Ruthenium-Based Metathesis CatalystsSimilar in reactivity to the Grubbs 2nd Generation Catalyst, but slower to initiate. This catalyst has broad utility.1,2,3Catalyst for:
• Ring-closing metathesis reactions4
• Ruthenium-catalyzed tandem enyne cross metathesis/cyclopropanation5
• Ruthenium-catalyzed stereoselective tandem cross-metathesis/Wittig olefination6
• Cross and ring-closing metatheses7
• Olefin cross-metathesis catalyzed by ruthenium alkylidene complexes8

Description (简体中文)

Other Notes
不接受大宗订购
包装
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
美国专利 5,969,170 和 7,329,758（以及上述专利的相关国外等同专利）均适用。销售该产品可向购买者转让限制使用研究许可。有关该许可的完整详细内容，请访问 sigma-aldrich.com/materialicense。如有疑问，请发送邮件至 aldrich@sial.com 与我们联系，或发送至 info@materia-inc.com 联系 Materia。
Application
Metathesis: Ruthenium-Based Metathesis CatalystsSimilar in reactivity to the Grubbs 2nd Generation Catalyst, but slower to initiate. This catalyst has broad utility.1,2,3Catalyst for:
• Ring-closing metathesis reactions4
• Ruthenium-catalyzed tandem enyne cross metathesis/cyclopropanation5
• Ruthenium-catalyzed stereoselective tandem cross-metathesis/Wittig olefination6
• Cross and ring-closing metatheses7
• Olefin cross-metathesis catalyzed by ruthenium alkylidene complexes8