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(S)-(-)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether_Molecular_structure_CAS_848821-58-9)
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(S)-(-)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether

Catalog No. 677183 Name Sigma Aldrich
CAS Number 848821-58-9 Website http://www.sigmaaldrich.com
M. F. C20H27NOSi Telephone 1-800-521-8956
M. W. 325.51998 Fax
Purity 95% Email
Storage Chembase ID: 140955

SYNONYMS

Title
(S)-(-)-α,α-二苯基-2-吡咯烷甲醇三甲基硅基醚
IUPAC name
(2S)-2-{diphenyl[(trimethylsilyl)oxy]methyl}pyrrolidine
IUPAC Traditional name
(2S)-2-{diphenyl[(trimethylsilyl)oxy]methyl}pyrrolidine
Synonyms
(S)-2-[Diphenyl(trimethylsilanyloxy)methyl]pyrrolidine
(2S)-2-[二苯基[(三甲基硅酯)氧基]甲基]吡咯烷
(2S)-2-[Diphenyl[(trimethylsilyl)oxy]methyl]pyrrolidine
(S)-α,α-Diphenylprolinol trimethylsilyl ether
(S)-α,α-二苯基脯氨醇三甲基硅基醚
(S)-2-[二苯基(三甲基硅烷氧基)甲基]吡咯烷

DATABASE IDS

MDL Number MFCD08690083
PubChem SID 24885354
CAS Number 848821-58-9

PROPERTIES

Empirical Formula (Hill Notation) C20H27NOSi
Purity 95%
Density 1.0459 g/mL at 25 °C
Flash Point >110 °C
Flash Point >230 °F
Optical Rotation [α]22/D -50°, c = 1 in chloroform
Refractive Index n20/D 1.5513
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26
Storage Temperature 2-8°C
German water hazard class 3

DETAILS

Description (English)
Application
Organocatalyst for 3-component reactions,1,2 and Robinson annulation of α,β-unsaturated aldehydes.3
Packaging
1, 5 g in glass bottle
Description (简体中文)
Application
三组分反应1,2和 α,β-不饱和醛的 Robinson 环化反应的有机催化剂。3
包装
1, 5 g in glass bottle

REFERENCES