Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct

• Catalog No.: 682101
• CAS Number: 137203-34-0
• M. F.: C12H30Al2N2
• M. W.: 256.343076

SYNONYMS

• Title: DABAL-三甲基铝
• IUPAC name: 1,4-diazabicyclo[2.2.2]octane; bis(trimethylalumane)
• IUPAC Traditional name: dabco; bis(trimethylaluminium)
• Synonyms: DABAL-trimethylaluminum; DABAL-Me3; 三亚乙基二胺基双三甲基铝; 双(三甲基铝)-1,4-二氮杂双环[2.2.2]辛烷加合物; Bis(trimethylaluminum)-DABCO® adduct; Triethylenediaminine bis(trimethylaluminum); 双(三甲基铝)-DABCO® 加合物

DATABASE IDS

• CAS Number: 137203-34-0
• PubChem SID: 24885678
• MDL Number: MFCD09265160

PROPERTIES

• Linear Formula: (CH3)3Al · C6H12N2 · Al(CH3)3
• Melting Point: >250 °C
• GHS Signal Word: Danger
• GHS Hazard statements: H260-H302-H315-H319-H335
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Harmful (Xn)
• Personal Protective Equipment: Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• GHS Precautionary statements: P223-P231 + P232-P261-P305 + P351 + P338-P370 + P378-P422
• RID/ADR: UN 3395 4.3/PG 1
• Risk Statements: 14-15-22-36/37/38
• Safety Statements: 16-26-43
• Supplemental Hazard Statements: Reacts violently with water.
• Hazard Class: 4.3
• UN Number: 3395
• Packing Group: 1
• German water hazard class: 3

DETAILS

Description (English)

Application
A more stable alternative to trimethylaluminum for use in numerous reactions including methylations of aldehydes and imines, methylations of aryl and vinyl halides, conjugate addition to enones, and amide bond formation.1
DABAL-Me3: An Air Stable "Methyl Anion"
Packaging
1, 5 g in glass bottle
General description
Product is air and moisture sensitive. Handle and store under a dry, inert atmosphere.
Legal Information
DABCO is a registered trademark of Air Products & Chemicals, Inc.

Description (简体中文)

Application
三甲基铝的非自燃替代物，可用于多种反应包括醛和亚胺的甲基化，芳基卤化物和乙烯基卤化物的甲基化，烯酮的共轭加成和酰胺键的形成。1
DABAL-Me3: An Air Stable "Methyl Anion"
包装
1, 5 g in glass bottle
General description
Product is air and moisture sensitive. Handle and store under a dry, inert atmosphere.
法律信息
DABCO 注册商标 Air Products & Chemicals, Inc.