(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine

• Catalog No.: 665363
• CAS Number: 415918-91-1
• M. F.: C36H50NO2P
• M. W.: 559.761461
• Purity: 97% (HPLC)

SYNONYMS

• Title: (S,R,R)-(+)-(3,5-二氧杂-4-磷杂环庚二烯并[2,1-a:3,4-a′]二萘-4-基)二(1-苯基乙基)胺
• IUPAC name: N,N-bis[(1R)-1-phenylethyl]-12,14-dioxa-13-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosan-13-amine
• IUPAC Traditional name: N,N-bis[(1R)-1-phenylethyl]-12,14-dioxa-13-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosan-13-amine
• Synonyms: (+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine, (11bS)

DATABASE IDS

• CAS Number: 415918-91-1
• MDL Number: MFCD08561138
• PubChem SID: 24884733

PROPERTIES

• Empirical Formula (Hill Notation): C36H30NO2P
• Purity: 97% (HPLC)
• Melting Point: 102-103 °C
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Chiral phosphoramidite ligand used in a highly enantioselective copper-catalyzed conjugate addition of diakylzincs to a variety of Michael acceptors.1,2,3 Also used in a palladium-catalyzed diethylzinc mediated umpolung allylation.4
DSM MonoPhos Family of Highly Efficient Privileged Ligands
Packaging
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
Sold under license from DSM for research purposes only.

Description (简体中文)

Application
手性亚磷酰胺配体，用于铜催化的高对映选择性共轭加成反应，该反应可将二烷基锌加成到各种 Michael 受体。1,2,3也可用于二乙基锌介导的钯催化极性反转烯丙基化反应。4
DSM MonoPhos Family of Highly Efficient Privileged Ligands
包装
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
经 DSM 授权销售，仅供研究使用。