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Bis(cyclooctadiene)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate_Molecular_structure_CAS_666826-16-0)
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Bis(cyclooctadiene)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

Catalog No. 693774 Name Sigma Aldrich
CAS Number 666826-16-0 Website http://www.sigmaaldrich.com
M. F. C48H36BF24Ir Telephone 1-800-521-8956
M. W. 1271.7891168 Fax
Purity Email
Storage Chembase ID: 140815

SYNONYMS

Title
双(环辛二烯)四(3,5-双(三氟甲基)苯基)硼酸铱(I)
IUPAC name
iridium(1+) ion bis(cycloocta-1,5-diene) tetrakis[3,5-bis(trifluoromethyl)phenyl]boranuide
IUPAC Traditional name
iridium(1+) ion bis(1,5-cyclooctadiene) tetrakis[3,5-bis(trifluoromethyl)phenyl]boranuide

DATABASE IDS

MDL Number MFCD10567389
CAS Number 666826-16-0

PROPERTIES

Linear Formula (Ir(C8H12)2)+ (B(C8H3F6)4)-
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26
German water hazard class 3

DETAILS

Description (English)
Packaging
2 g in glass bottle
500 mg in glass bottle
Application
Catalyst for:
• Asymmetric hydrogenation reactions1
• Directed cyclodehydration reaction2
• Direct prenylation via C-H oxidative addition-allene insertion3
• Double intramolecular hydroalkoxylation4
• Intramolecular hydroamination reactions5
• Directed C-H bond cleavage6
• Imine vinylation reactions7Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Description (简体中文)
包装
2 g in glass bottle
500 mg in glass bottle
Application
Catalyst for:
• Asymmetric hydrogenation reactions1
• Directed cyclodehydration reaction2
• Direct prenylation via C-H oxidative addition-allene insertion3
• Double intramolecular hydroalkoxylation4
• Intramolecular hydroamination reactions5
• Directed C-H bond cleavage6
• Imine vinylation reactions7Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

REFERENCES