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(S)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate_Molecular_structure_CAS_874948-63-7)
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(S)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

Catalog No. 689785 Name Sigma Aldrich
CAS Number 874948-63-7 Website http://www.sigmaaldrich.com
M. F. C50H57O4P Telephone 1-800-521-8956
M. W. 752.958941 Fax
Purity ≥97.5% (HPLC) Email
Storage Chembase ID: 140813

SYNONYMS

Title
(S)-3,3′-双(2,4,6-三异丙基苯基)-1,1′-联萘-2,2′-双磷酸氢酯
IUPAC name
13-hydroxy-10,16-bis[2,4,6-tris(propan-2-yl)phenyl]-12,14-dioxa-13λ5-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-13-one
IUPAC Traditional name
13-hydroxy-10,16-bis(2,4,6-triisopropylphenyl)-12,14-dioxa-13λ5-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-13-one
Synonyms
(11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin 4-oxide
(S)-3,3′-双(2,4,6-三异丙基苯基)-1,1′-二-2-萘酚环一磷酸酯
(S)-TRIP
(S)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-bi-2-naphthol cyclic monophosphate
(11bS)-4-羟基-2,6-双[2,4,6-三(1-甲基乙基)苯基]二萘并[2,1-d:1′,2′-f]-1,3,2-二氧杂膦 4-氧化物

DATABASE IDS

CAS Number 874948-63-7
MDL Number MFCD10567009

PROPERTIES

Empirical Formula (Hill Notation) C50H57O4P
Optical Purity enantiomeric excess: ≥97.5% (HPLC)
Purity ≥97.5% (HPLC)
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Packaging
100, 500 mg in glass bottle
Protocols & Applications
Reductive Amination using BINOL-Derived Chiral Phosphoric Acids
Description (简体中文)
包装
100, 500 mg in glass bottle
Protocols & Applications
Reductive Amination using BINOL-Derived Chiral Phosphoric Acids

REFERENCES