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(-)-Ipc2B(allyl)borane solution_Molecular_structure_CAS_85116-38-7)
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(-)-Ipc2B(allyl)borane solution

Catalog No. 678538 Name Sigma Aldrich
CAS Number 85116-38-7 Website http://www.sigmaaldrich.com
M. F. C23H39B Telephone 1-800-521-8956
M. W. 326.36676 Fax
Purity Email
Storage Chembase ID: 140744

SYNONYMS

Title
(-)-Ipc2B(烯丙基)硼烷
IUPAC name
prop-2-en-1-ylbis[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl]borane
IUPAC Traditional name
prop-2-en-1-ylbis[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl]borane
Synonyms
(-)-B-二异松莰烯基烯丙基硼
(-)-B-Allyldiisopinocampheylborane solution

DATABASE IDS

CAS Number 85116-38-7
PubChem SID 24885432

PROPERTIES

Concentration 1 M in pentane
Linear Formula (C10H17)2BCH2CH=CH2
Boiling Point 35-36 °C
Density 0.638 g/mL at 25 °C
Flash Point -49 °C
Flash Point -56.2 °F
Optical Rotation [α]20/D -35 to ±5°, c = 1
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Pictograms GHS08
GHS Pictograms GHS09
GHS Signal Word Danger
GHS Hazard statements H224-H304-H315-H319-H335 + H336-H411
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Harmful Harmful (Xn)
European Hazard Symbols Nature polluting Nature polluting (N)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
GHS Precautionary statements P210-P261-P273-P301 + P310-P305 + P351 + P338-P331
RID/ADR UN 1265 3/PG 2
Risk Statements 11-36/37/38-51/53-65-67
Safety Statements 16-26-61-62
Storage Temperature -20°C
Hazard Class 3
UN Number 1265
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Application
Convenient, salt-free, stable solution of a chiral allyl borane for asymmetric allylation of aldehydes leading to chiral homoallylic alcohols.1,2
General description
Material may become hazy upon cooler storage, this will not affect use
Packaging
5, 25 mL in ampule
Description (简体中文)
Application
方便、无盐且稳定的手性烯丙基硼烷溶液,用于醛的不对称烯丙基化反应,生成手性高烯丙醇。1,2
General description
本品冷却储藏时可能会变浑浊,不影响使用
包装
5, 25 mL in ampule

REFERENCES