(-)-Ipc2B(allyl)borane solution

• Catalog No.: 678538
• CAS Number: 85116-38-7
• M. F.: C23H39B
• M. W.: 326.36676

SYNONYMS

• Title: (-)-Ipc2B(烯丙基)硼烷
• IUPAC name: prop-2-en-1-ylbis[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl]borane
• IUPAC Traditional name: prop-2-en-1-ylbis[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl]borane
• Synonyms: (-)-B-二异松莰烯基烯丙基硼; (-)-B-Allyldiisopinocampheylborane solution

DATABASE IDS

• CAS Number: 85116-38-7
• PubChem SID: 24885432

PROPERTIES

• Concentration: 1 M in pentane
• Linear Formula: (C10H17)2BCH2CH=CH2
• Boiling Point: 35-36 °C
• Density: 0.638 g/mL at 25 °C
• Flash Point: -49 °C
• Flash Point: -56.2 °F
• Optical Rotation: [α]20/D -35 to ±5°, c = 1
• GHS Signal Word: Danger
• GHS Hazard statements: H224-H304-H315-H319-H335 + H336-H411
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Harmful (Xn)
• European Hazard Symbols: Nature polluting (N)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
• GHS Precautionary statements: P210-P261-P273-P301 + P310-P305 + P351 + P338-P331
• RID/ADR: UN 1265 3/PG 2
• Risk Statements: 11-36/37/38-51/53-65-67
• Safety Statements: 16-26-61-62
• Storage Temperature: -20°C
• Hazard Class: 3
• UN Number: 1265
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Application
Convenient, salt-free, stable solution of a chiral allyl borane for asymmetric allylation of aldehydes leading to chiral homoallylic alcohols.1,2
General description
Material may become hazy upon cooler storage, this will not affect use
Packaging
5, 25 mL in ampule

Description (简体中文)

Application
方便、无盐且稳定的手性烯丙基硼烷溶液，用于醛的不对称烯丙基化反应，生成手性高烯丙醇。1,2
General description
本品冷却储藏时可能会变浑浊，不影响使用
包装
5, 25 mL in ampule