N-tert-Butylbenzenesulfenamide

• Catalog No.: 681792
• CAS Number: 19117-31-8
• M. F.: C10H15NS
• M. W.: 181.2978
• Purity: 97%

SYNONYMS

• Title: N-叔丁基苯亚磺酰胺
• IUPAC name: tert-butyl(phenylsulfanyl)amine
• IUPAC Traditional name: tert-butyl(phenylsulfanyl)amine
• Synonyms: N-(1,1-Dimethylethyl)benzenesulfenamide; N-叔丁基苯磺酰胺; N-(1,1-二甲基乙基)苯亚磺酰胺; 2-Methyl-N-(phenylthio)propan-2-amine

DATABASE IDS

• CAS Number: 19117-31-8
• PubChem SID: 24885655
• MDL Number: MFCD03844776

PROPERTIES

• Purity: 97%
• Empirical Formula (Hill Notation): C10H15NS
• Boiling Point: 57-60 °C/0.3 mmHg
• Density: 0.997 g/mL at 25 °C
• Flash Point: 96 °C
• Flash Point: 204.8 °F
• Refractive Index: n20/D 1.5457
• Personal Protective Equipment: Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
• German water hazard class: 3

DETAILS

Description (English)

Application
In the presence of NCS, this sulfenamide catalyzes the mild and selective oxidation of primary and secondary alcohols to the respective aldehydes and ketones.3
Reactant for:
• Anti-SN2′ Mitsunobu reaction with chiral hydroxy-alpha-alkenylsilanes to give vinylsilanes1
• Anodic oxidation reactions2
Packaging
1, 5 g in glass bottle

Description (简体中文)

Application
在 NCS 存在的条件下，这种亚磺酰胺可催化伯醇和仲醇的温和选择性氧化反应，分别生成醛和酮。3
Reactant for:
• Anti-SN2′ Mitsunobu reaction with chiral hydroxy-alpha-alkenylsilanes to give vinylsilanes1
• Anodic oxidation reactions2
包装
1, 5 g in glass bottle