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(S,S,S)-DiazaPhos-PPE

Catalog No. 685240 Name Sigma Aldrich
CAS Number 615538-63-1 Website http://www.sigmaaldrich.com
M. F. C46H39N4O4P Telephone 1-800-521-8956
M. W. 742.800021 Fax
Purity Email
Storage Chembase ID: 140686

SYNONYMS

Title
2,2′-[(1S,3S)-2,3,5,10-四氢-5,10-二氧-2-苯基-1H-[1,2,4]二氮杂磷杂环戊烷[1,2-b]酞嗪-1,3-二基]双[N-(1S)-1-苯乙基]苯酰胺]
IUPAC name
2-[(1S)-5,10-dioxo-2-phenyl-3-(2-{[(1S)-1-phenylethyl]carbamoyl}phenyl)-1H,2H,3H,5H,10H-[1,2,4]diazaphospholo[1,2-b]phthalazin-1-yl]-N-[(1S)-1-phenylethyl]benzamide
IUPAC Traditional name
2-[(1S)-5,10-dioxo-2-phenyl-3-(2-{[(1S)-1-phenylethyl]carbamoyl}phenyl)-1H,3H-[1,2,4]diazaphospholo[1,2-b]phthalazin-1-yl]-N-[(1S)-1-phenylethyl]benzamide
Synonyms
2,2′-[(1S,3S)-2,3,5,10-Tetrahydro-5,10-dioxo-2-phenyl-1H-[1,2,4]diazaphospholo[1,2-b]phthalazine-1,3-diyl]bis[N-(1S)-1-phenylethyl]benzamide
(S,S,S)-DiazaPhos-PPE

DATABASE IDS

CAS Number 615538-63-1

PROPERTIES

Empirical Formula (Hill Notation) C46H39N4O4P
Melting Point 134-159 °C
Optical Rotation [α]20/D -27°, c = 1 in chloroform
MSDS Link Download

DETAILS

Description (English)
Application
Diazaphospholane ligands display excellent levels of conversion and selectivity in Rh-catalyzed asymmetric hydroformylation reactions.1,2
Diazaphospholane Ligands for Catalytic Asymmetric Transformations
Packaging
100, 500 mg in glass bottle
Legal Information
Product is sold for R&D purpose only and use by end user in the manufacture of products of commerce is not permitted. Product is sold in association with DowpharmaSM a business unit of The Dow Chemical Company. U.S. Pat. 7,071,357B.
Description (简体中文)
Application
二氮杂磷杂环戊烷配体在铑催化的不对称氢甲酰化反应中显示出优良的转化水平和选择性。1,2
Diazaphospholane Ligands for Catalytic Asymmetric Transformations
包装
100, 500 mg in glass bottle
Legal Information
销售的产品仅限于研发目的并且不允许终端用户用于商品生产。与 DowpharmaSM(Dow Chemical Company 的业务单位)联合销售产品。美国专利 7,071,357B。

REFERENCES