(R,R,S)-DiazaPhos-PPE

• Catalog No.: 685089
• CAS Number: 615257-74-4
• M. F.: C46H39N4O4P
• M. W.: 742.800021

SYNONYMS

• Title: 2,2′-[(1R,3R)-2,3,5,10-四氢-5,10-二氧-2-苯基-1H-[1,2,4]二氮杂磷杂环戊烷[1,2-b]酞嗪-1,3-二基]双[N-[(1S)-1-苯乙基]苯甲酰胺]
• IUPAC name: 2-[(1R,3R)-5,10-dioxo-2-phenyl-3-(2-{[(1S)-1-phenylethyl]carbamoyl}phenyl)-1H,2H,3H,5H,10H-[1,2,4]diazaphospholo[1,2-b]phthalazin-1-yl]-N-[(1S)-1-phenylethyl]benzamide
• IUPAC Traditional name: 2-[(1R,3R)-5,10-dioxo-2-phenyl-3-(2-{[(1S)-1-phenylethyl]carbamoyl}phenyl)-1H,3H-[1,2,4]diazaphospholo[1,2-b]phthalazin-1-yl]-N-[(1S)-1-phenylethyl]benzamide
• Synonyms: 2,2′-[(1R,3R)-2,3,5,10-Tetrahydro-5,10-dioxo-2-phenyl-1H-[1,2,4]diazaphospholo[1,2-b]phthalazine-1,3-diyl]bis[N-[(1S)-1-phenylethyl]benzamide]; (R,R,S)-DiazaPhos-PPE

DATABASE IDS

• MDL Number: MFCD10566993
• CAS Number: 615257-74-4

PROPERTIES

• Empirical Formula (Hill Notation): C46H39N4O4P
• Melting Point: 258-262 °C
• Optical Rotation: [α]20/D +105°, c = 1 in THF
• German water hazard class: 3

DETAILS

Description (English)

Application
Diazaphospholane ligands display excellent levels of conversion and selectivity in Rh-catalyzed asymmetric hydroformylation reactions.1,2
Diazaphospholane Ligands for Catalytic Asymmetric Transformations
Packaging
100, 500 mg in glass bottle
Legal Information
Product is sold for R&D purpose only and use by end user in the manfacture of products of commerce is not permitted. Product is sold in association with DowpharmaSM a business unit of The Dow Chemical Company. U.S. Pat. 7,071,357B.

Description (简体中文)

Application
二氮杂磷杂环戊烷配体在铑催化的不对称氢甲酰化反应中显示出优良的转化水平和选择性。1,2
Diazaphospholane Ligands for Catalytic Asymmetric Transformations
包装
100, 500 mg in glass bottle
Legal Information
销售的产品仅限于研发目的并且不允许终端用户用于商品生产。与 DowpharmaSM（Dow Chemical Company 的业务单位）联合销售产品。美国专利 7,071,357B。