9-Borabicyclo[3.3.1]nonane solution

• Catalog No.: 151076
• CAS Number: 280-64-8
• M. F.: C8H15B
• M. W.: 122.0157

SYNONYMS

• Title: 9-硼双环[3.3.1]壬烷 溶液
• IUPAC name: (1s,5s)-9-borabicyclo[3.3.1]nonane
• IUPAC Traditional name: (1s,5s)-9-borabicyclo[3.3.1]nonane
• Synonyms: 9-BBN

DATABASE IDS

• CAS Number: 280-64-8
• PubChem SID: 24849089
• Beilstein Number: 605509
• MDL Number: MFCD00074742

PROPERTIES

• Concentration: 0.5 M in THF
• Empirical Formula (Hill Notation): C8H15B
• Density: 0.894 g/mL at 25 °C
• Flash Point: -17 °C
• Flash Point: 1.4 °F
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H260-H319-H335
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Irritant (Xi)
• GHS Precautionary statements: P210-P223-P231 + P232-P261-P370 + P378-P422
• RID/ADR: UN 3399 4.3/PG 1
• Risk Statements: 11-14/15-19-36/37
• Safety Statements: 16-26-43
• Supplemental Hazard Statements: May form explosive peroxides.
• Hazard Class: 4.3
• UN Number: 3399
• Packing Group: 1
• German water hazard class: 3

DETAILS

Description (English)

Application
Differentiation of symmetrical diols by reduction of the corresponding cyclic acetals with 9-BBN.6
Selective hydroboration reduction reagent.
Protecting group for alkenes†Reactant for:
• Linear SPPS synthesis of ubiquitin derivatives1
• Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides2
• Intramolecular insertion of alkenes into palladium-nitrogen bonds3
• Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast4
• Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids5
Packaging
4×25, 100, 800 mL in Sure/Seal™
8, 18 L in Kilo-Lab™
View returnable container options.

Description (简体中文)

Application
使用 9-BBN 对相应环状缩醛进行还原以鉴别对称二醇。6
选择性硼氢化还原试剂。
Protecting group for alkenes†Reactant for:
• Linear SPPS synthesis of ubiquitin derivatives1
• Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides2
• Intramolecular insertion of alkenes into palladium-nitrogen bonds3
• Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast4
• Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids5
包装
4×25, 100, 800 mL in Sure/Seal™
8, 18 L in Kilo-Lab™
View returnable container options.