B-Methoxy-10-trimethylsilyl-9-borabicyclo(3.3.2)decane

• Catalog No.: 676667
• CAS Number: 848617-93-6
• M. F.: C13H27BOSi
• M. W.: 238.24938
• Purity: 95%

SYNONYMS

• Title: B-甲氧基-10-三甲基甲硅烷基-9-硼二环(3.3.2)癸烷
• IUPAC name: {9-methoxy-9-borabicyclo[3.3.2]decan-10-yl}trimethylsilane
• IUPAC Traditional name: {9-methoxy-9-borabicyclo[3.3.2]decan-10-yl}trimethylsilane
• Synonyms: 10-TMS-9-Borabicyclo[3.3.2]decane; 10-TMS-9-BBD; 9-甲氧基-10-三甲基甲硅烷基-9-硼二环(3.3.2)癸烷; 9-Methoxy-10-trimethylsilanyl-9-borabicyclo(3.3.2)decane

DATABASE IDS

• PubChem SID: 24885322
• CAS Number: 848617-93-6

PROPERTIES

• Risk Statements: 10-14/15
• Safety Statements: 7-43
• Supplemental Hazard Statements: Reacts violently with water.
• Hazard Class: 4.3
• UN Number: 3148
• Packing Group: 2
• German water hazard class: 3
• GHS Signal Word: Danger
• GHS Hazard statements: H226-H261
• European Hazard Symbols: Flammable (F)
• Personal Protective Equipment: Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
• GHS Precautionary statements: P231 + P232-P422
• RID/ADR: UN 3148 4.3/PG 2
• Empirical Formula (Hill Notation): C13H27BOSi
• Purity: 95%
• Boiling Point: 85 °C/0.4 mmHg
• Density: 0.934 g/mL at 25 °C
• Flash Point: 59 °C
• Flash Point: 138.2 °F
• Refractive Index: n20/D 1.494

DETAILS

Description (English)

Packaging
5, 25 g in glass bottle
Application
Soderquist Reagents: For allylboration, allenylboration, propargylborationReactant for:
• Palladium-catalyzed allylation reaction1
• Hydroboration of allenes2
• Stereoselective γ-methoxyallylation reactions3
• Asymmetric carboborylation reactions4
• Insertion and borotropic rearrangement reactions5
• Asymmetric Michael addition reactions6
• Asymmetric propargylation of aldehydes7
• Asymmetric allenylboration reactions8

Description (简体中文)

包装
5, 25 g in glass bottle
Application
Soderquist Reagents: For allylboration, allenylboration, propargylborationReactant for:
• Palladium-catalyzed allylation reaction1
• Hydroboration of allenes2
• Stereoselective γ-methoxyallylation reactions3
• Asymmetric carboborylation reactions4
• Insertion and borotropic rearrangement reactions5
• Asymmetric Michael addition reactions6
• Asymmetric propargylation of aldehydes7
• Asymmetric allenylboration reactions8