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B-Methoxy-10-trimethylsilyl-9-borabicyclo(3.3.2)decane_Molecular_structure_CAS_848617-93-6)
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B-Methoxy-10-trimethylsilyl-9-borabicyclo(3.3.2)decane

Catalog No. 676667 Name Sigma Aldrich
CAS Number 848617-93-6 Website http://www.sigmaaldrich.com
M. F. C13H27BOSi Telephone 1-800-521-8956
M. W. 238.24938 Fax
Purity 95% Email
Storage Chembase ID: 140662

SYNONYMS

Title
B-甲氧基-10-三甲基甲硅烷基-9-硼二环(3.3.2)癸烷
IUPAC name
{9-methoxy-9-borabicyclo[3.3.2]decan-10-yl}trimethylsilane
IUPAC Traditional name
{9-methoxy-9-borabicyclo[3.3.2]decan-10-yl}trimethylsilane
Synonyms
10-TMS-9-Borabicyclo[3.3.2]decane
10-TMS-9-BBD
9-甲氧基-10-三甲基甲硅烷基-9-硼二环(3.3.2)癸烷
9-Methoxy-10-trimethylsilanyl-9-borabicyclo(3.3.2)decane

DATABASE IDS

PubChem SID 24885322
CAS Number 848617-93-6

PROPERTIES

Risk Statements 10-14/15
Safety Statements 7-43
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 4.3
UN Number 3148
Packing Group 2
German water hazard class 3
GHS Pictograms GHS02
GHS Signal Word Danger
GHS Hazard statements H226-H261
European Hazard Symbols Flammable Flammable (F)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
GHS Precautionary statements P231 + P232-P422
RID/ADR UN 3148 4.3/PG 2
Empirical Formula (Hill Notation) C13H27BOSi
Purity 95%
Boiling Point 85 °C/0.4 mmHg
Density 0.934 g/mL at 25 °C
Flash Point 59 °C
Flash Point 138.2 °F
Refractive Index n20/D 1.494

DETAILS

Description (English)
Packaging
5, 25 g in glass bottle
Application
Soderquist Reagents: For allylboration, allenylboration, propargylborationReactant for:
• Palladium-catalyzed allylation reaction1
• Hydroboration of allenes2
• Stereoselective γ-methoxyallylation reactions3
• Asymmetric carboborylation reactions4
• Insertion and borotropic rearrangement reactions5
• Asymmetric Michael addition reactions6
• Asymmetric propargylation of aldehydes7
• Asymmetric allenylboration reactions8
Description (简体中文)
包装
5, 25 g in glass bottle
Application
Soderquist Reagents: For allylboration, allenylboration, propargylborationReactant for:
• Palladium-catalyzed allylation reaction1
• Hydroboration of allenes2
• Stereoselective γ-methoxyallylation reactions3
• Asymmetric carboborylation reactions4
• Insertion and borotropic rearrangement reactions5
• Asymmetric Michael addition reactions6
• Asymmetric propargylation of aldehydes7
• Asymmetric allenylboration reactions8

REFERENCES