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Cumene hydroperoxide

Catalog No. 247502 Name Sigma Aldrich
CAS Number 80-15-9 Website http://www.sigmaaldrich.com
M. F. C9H12O2 Telephone 1-800-521-8956
M. W. 152.19038 Fax
Purity 80% Email
Storage Chembase ID: 110155

SYNONYMS

Title
过氧化氢异丙苯
IUPAC name
2-phenylpropane-2-peroxol
IUPAC Traditional name
cumene hydroperoxide
Synonyms
α,α-二甲基苄基过氧化氢
α,α-Dimethylbenzyl hydroperoxide

DATABASE IDS

Beilstein Number 1908117
MDL Number MFCD00002129
CAS Number 80-15-9
PubChem SID 24854872
EC Number 201-254-7

PROPERTIES

Grade technical grade
Linear Formula C6H5C(CH3)2OOH
Purity 80%
Boiling Point 100-101 °C/8 mmHg(lit.)
Density 1.03 g/mL at 25 °C
Flash Point 79 °C
Flash Point 174.2 °F
Refractive Index n20/D 1.5210
Vapor Density 5.4 (vs air)
Vapor Pressure <0.03 mmHg ( 20 °C)
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS06
GHS Pictograms GHS08
GHS Pictograms GHS09
GHS Signal Word Danger
GHS Hazard statements H242-H302-H312-H314-H331-H373-H411
European Hazard Symbols Oxidising Oxidising (O)
European Hazard Symbols Toxic Toxic (T)
European Hazard Symbols Nature polluting Nature polluting (N)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P220-P261-P273-P280-P305 + P351 + P338-P310
RID/ADR UN 3109 5.2
Risk Statements 7-21/22-23-34-48/20/22-51/53
RTECS MX2450000
Safety Statements 3/7-14-36/37/39-45-50-61
Hazard Class 5.2
UN Number 3109
German water hazard class 2

DETAILS

Description (English)
Packaging
5, 100, 500 g in poly bottle
Application
Epoxidation reagent for allylic alcohols1 and fatty acid esters,2 as an initiator for radical polymerization.3
Protocols & Applications
Asymmetric Epoxidation of Allylic Alcohols
Asymmetric Epoxidation of Homoallylic Alcohols
Asymmetric Ketone Hydrogenation
Asymmetric Transfer Hydrogenation
Description (简体中文)
包装
5, 100, 500 g in poly bottle
Application
环氧化试剂,用于烯丙醇1和脂肪酸酯,2作为自由基聚合反应的引发剂。3
Protocols & Applications
Asymmetric Epoxidation of Allylic Alcohols
Asymmetric Epoxidation of Homoallylic Alcohols
Asymmetric Ketone Hydrogenation
Asymmetric Transfer Hydrogenation

REFERENCES