(R)-C3-TunePhos-ruthenium complex

• Catalog No.: 659711
• CAS Number: 905709-79-7
• M. F.: C49H46Cl2O2P2Ru
• M. W.: 900.811862

SYNONYMS

• Title: (R)-C3-TunePhos-钌络合物
• IUPAC name: 1-methyl-4-(propan-2-yl)benzene [17-(diphenylphosphanyl)-8,12-dioxatricyclo[11.4.0.0^2,^7]heptadeca-1(13),2(7),3,5,14,16-hexaen-3-yl]diphenylphosphane chlororutheniumylium chloride
• IUPAC Traditional name: [17-(diphenylphosphanyl)-8,12-dioxatricyclo[11.4.0.0^2,^7]heptadeca-1(13),2(7),3,5,14,16-hexaen-3-yl]diphenylphosphane chlororutheniumylium cymene chloride
• Synonyms: [Chloro(R)-C3-TunePhos)(p-cymene)ruthenium(II)] chloride; [氯(R)-C3-TunePhos)(p-异丙基甲苯基)钌(II)]氯化物

DATABASE IDS

• MDL Number: MFCD07782001
• PubChem SID: 24884439
• CAS Number: 905709-79-7

PROPERTIES

• Empirical Formula (Hill Notation): C49H46Cl2O2P2Ru
• Melting Point: >300 °C
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Provides comparable or superior enantioselectivities and catalytic abilities to BINAP in Ru-catalyzed asymmetric hydrogenations of β-keto esters,1 cyclic β-(acylamino)acrylates2 and α-phthalimide ketones.3
Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
Packaging
100, 500 mg in glass bottle

Description (简体中文)

Application
在钌催化的 β-酮酯1、环 β-(酰胺基)丙烯酸酯2和 α-邻苯二甲酰亚胺酮3的不对称性氢化反应中可以提供与 BINAP 相当或更好的对映选择性以及催化能力。
Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
包装
100, 500 mg in glass bottle