(R)-(-)-COP-Cl Catalyst

• Catalog No.: 661791
• CAS Number: 612065-00-6
• M. F.: C78H68Cl2Co2N2O2Pd2
• M. W.: 1466.99912

SYNONYMS

• Title: (R)-(-)-COP-Cl 催化剂
• IUPAC name: bis(λ^2-cobalt(2+) ion) bis(3-[(4R)-4-(propan-2-yl)-4,5-dihydro-1,3-oxazol-2-yl]cyclopenta-2,4-dien-1-ide) cyclodipalladachlorane-1,3-bis(ylium) bis(tetraphenylcyclobut-3-ene-1,2-diide)
• IUPAC Traditional name: bis(λ^2-cobalt(2+) ion) bis(3-[(4R)-4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl]cyclopenta-2,4-dien-1-ide) cyclodipalladachlorane-1,3-bis(ylium) bis(tetraphenylcyclobut-3-ene-1,2-diide)
• Synonyms: [Bis[μ-(chloro-κO:κO′)]dipalladium]bis[1,1′,1′′,1′′′-(η4-1,3-cyclobutadiene-1,2,3,4-tetrayl) tetrakis[benzene]]bis[μ-[(1-η:1,2,3,4,5-η)-2-[(4R)-4,5-dihydro-4-(1-methylethyl)-2-oxazolyl-κN3]-2,4-cyclopentadien-1-ylidene]]dicobalt; Di-μ-chlorobis[η5-(R)-(pR)-2-(2′-(4′-methylethyl)oxazolinyl)cyclopentadienyl,1-C,3′-N)(η4-tetraphenylcyclobutadiene)cobalt]dipalladium; 二-μ-氯双[η5-(R)-(pR)-2-(2′-(4′-甲基乙基)噁唑啉基)环戊二烯基,1-C,3′-N)(η4-四苯基环丁二烯)钴]二钯; [双[μ-(氯-κO:κO′)]二钯]双[1,1′,1′′,1′′′-(η4-1,3-环丁二烯-1,2,3,4-四基)四[苯]]双[μ-[(1-η:1,2,3,4,5-η)-2-[(4R)-4,5-二氢-4-(1-甲基乙基)-2-噁唑基-κN3]-2,4-环戊二烯-1-亚基]]二钴

DATABASE IDS

• MDL Number: MFCD08705287
• CAS Number: 612065-00-6

PROPERTIES

• Empirical Formula (Hill Notation): C78H66Cl2Co2N2O2Pd2
• Melting Point: 192-208 °C
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Catalyst employed in the rearrangement of allylic trichloracetimidates to allylic amines of high enantiopurity.4
Catalyst for:
• Stereoselective allylic substitution of Z-allylic trichloroacetimidates1
• Asymmetric synthesis of allylic thiol derivatives by rearrangement of linear prochiral O-allyl carbamothioates2
• Asymmetric aza-Claisen rearrangement3
• Enantioselective preparation of allylic trichloroacetamides via rearrangement of allylic trichloroacetimidates4
Packaging
100, 500 mg in glass bottle

Description (简体中文)

Application
用于钯催化重排三氯乙酰亚胺烯丙酯生成高对映纯烯丙胺的配体。4
Catalyst for:
• Stereoselective allylic substitution of Z-allylic trichloroacetimidates1
• Asymmetric synthesis of allylic thiol derivatives by rearrangement of linear prochiral O-allyl carbamothioates2
• Asymmetric aza-Claisen rearrangement3
• Enantioselective preparation of allylic trichloroacetamides via rearrangement of allylic trichloroacetimidates4
包装
100, 500 mg in glass bottle