Bis(tert-butylcarbonyloxy)iodobenzene

• Catalog No.: 662283
• CAS Number: 57357-20-7
• M. F.: C16H23IO4
• M. W.: 406.25589
• Purity: 97%

SYNONYMS

• Title: 双(叔丁基羰基氧)碘苯
• IUPAC name: [(2,2-dimethylpropanoyl)oxy](phenyl)-λ^3-iodanyl 2,2-dimethylpropanoate
• IUPAC Traditional name: [(2,2-dimethylpropanoyl)oxy](phenyl)-λ^3-iodanyl 2,2-dimethylpropanoate
• Synonyms: 二-(新戊酰氧)碘苯; 双(2,2-二甲基丙酸根-O)碘代苯; Bis(2,2-dimethylpropanoato-O)phenyliodide; 2,2-二甲基丙酸，苯基碘络合物; (Di-tert-butylcarbonyloxyiodo)benzol; 2,2-Dimethylpropanoic acid, phenyliodine complex; Di-(Pivaloyloxy)iodobenzene; (二-叔丁基羰基氧碘代)苯

DATABASE IDS

• PubChem SID: 24884583
• MDL Number: MFCD08276835
• CAS Number: 57357-20-7

PROPERTIES

• Empirical Formula (Hill Notation): C16H23IO4
• Purity: 97%
• Melting Point: 104-109 °C
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Hypervalent iodine reagent used with the Rh2(esp)2 catalyst (662623) in the amination of C-H bonds.7
Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H AminationReagent for:
• Preparation of α,β-unsaturated-γ-lactams via Rh-catalyzed C-H amination of allene carbamates, then Ru-catalyzed cyclocarbonylation1
• Palladium-catalyzed diamination2
• Preparation of functionalized bicyclic heterocyclic compounds by rhodium-catalyzed allene amidation and cyclization3
• Preparation of piperidine and pyrrolidine derivatives via copper-catalyzed intramolecular aminoacetoxylation of aminoolefins4
• C-H acyloxylation of arenes5
• Hypervalent iodine oxidant6
Packaging
5, 25 g in glass bottle

Description (简体中文)

Application
与 Rh2(esp)2 催化剂 (662623) 共同用于 C-H 键胺化的高价碘试剂。7
Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H AminationReagent for:
• Preparation of α,β-unsaturated-γ-lactams via Rh-catalyzed C-H amination of allene carbamates, then Ru-catalyzed cyclocarbonylation1
• Palladium-catalyzed diamination2
• Preparation of functionalized bicyclic heterocyclic compounds by rhodium-catalyzed allene amidation and cyclization3
• Preparation of piperidine and pyrrolidine derivatives via copper-catalyzed intramolecular aminoacetoxylation of aminoolefins4
• C-H acyloxylation of arenes5
• Hypervalent iodine oxidant6
包装
5, 25 g in glass bottle