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1,2-Bis[(2R,5R)-2,5-(dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate_Molecular_structure_CAS_305818-67-1)
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1,2-Bis[(2R,5R)-2,5-(dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate

Catalog No. 675555 Name Sigma Aldrich
CAS Number 305818-67-1 Website http://www.sigmaaldrich.com
M. F. C22H40BF4P2Rh Telephone 1-800-521-8956
M. W. 556.2106348 Fax
Purity Email
Storage Chembase ID: 140538

SYNONYMS

Title
1,2-双[(2R,5R)-2,5-(二甲基磷]乙烷(环辛二烯)四氟硼酸铑(I)
IUPAC name
λ1-rhodium(1+) ion (2R,5R)-1-{2-[(2R,5R)-2,5-dimethylphospholan-1-yl]ethyl}-2,5-dimethylphospholane cycloocta-1,5-diene tetrafluoroboranuide
IUPAC Traditional name
λ1-rhodium(1+) ion (2R,5R)-1-{2-[(2R,5R)-2,5-dimethylphospholan-1-yl]ethyl}-2,5-dimethylphospholane 1,5-cyclooctadiene tetrafluoroborate

DATABASE IDS

PubChem SID 24885288
CAS Number 305818-67-1

PROPERTIES

Empirical Formula (Hill Notation) C22H40BF4P2Rh
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26
German water hazard class 3

DETAILS

Description (English)
Packaging
100, 500 mg in glass bottle
Legal Information
Sold in collaboration with Kanata Chemical Technologies, Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.
Application
DuPhos and BPE Ligands: Highly Efficient Privileged LigandsCatalyst for:
• Preparation of substituted phenylalanine via asymmetric hydrogenation of N-acetyldehydroamino acid precursor1
• Enantioselective preparation of trifluoromethyl amino acids via asymmetric hydrogenation2
• Asymmetric hydrogenation of acetamidocinnamate3
Description (简体中文)
包装
100, 500 mg in glass bottle
Legal Information
与 Kanata Chemical Technologies, Inc. 联合销售,仅供研究使用。这些化合物由 E.I. du Pont de Nemours and Company 授权制造和销售,此许可不包括利用这些化合物制备在制药领域销售的产品的权利。
Application
DuPhos and BPE Ligands: Highly Efficient Privileged LigandsCatalyst for:
• Preparation of substituted phenylalanine via asymmetric hydrogenation of N-acetyldehydroamino acid precursor1
• Enantioselective preparation of trifluoromethyl amino acids via asymmetric hydrogenation2
• Asymmetric hydrogenation of acetamidocinnamate3

REFERENCES