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N-Isopropylidene-N′-2-nitrobenzenesulfonyl hydrazine_Molecular_structure_CAS_6655-27-2)
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N-Isopropylidene-N′-2-nitrobenzenesulfonyl hydrazine

Catalog No. 687855 Name Sigma Aldrich
CAS Number 6655-27-2 Website http://www.sigmaaldrich.com
M. F. C9H11N3O4S Telephone 1-800-521-8956
M. W. 257.26634 Fax
Purity 97% Email
Storage Chembase ID: 140519

SYNONYMS

Title
N-异亚丙基-N′-2-硝基苯磺酰肼
IUPAC name
2-nitro-N'-(propan-2-ylidene)benzene-1-sulfonohydrazide
IUPAC Traditional name
2-nitro-N'-(propan-2-ylidene)benzenesulfonohydrazide
Synonyms
IPNBSH
Acetone 2-nitrobenzenesulfonylhydrazone
2-(1-Methylethylidene)hydrazide-2-nitrobenzenesulfonic acid
Isopropylidenehydrazide o-nitro-benzenesulfonic acid
异亚丙基肼邻硝基苯磺酸

DATABASE IDS

MDL Number MFCD09800525
CAS Number 6655-27-2

PROPERTIES

Empirical Formula (Hill Notation) C9H11N3O4S
Purity 97%
Melting Point 131-135 °C
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Application
Reagent for allylic transposition and reduction of alcohols,5 as well as mild and stereoselective reduction of allylic carbonates and vinyl epoxides.3
IPNBSH A Reagent for the Simple Reduction of AlcoholsReactant for synthesis of:
• (-)-Acylfulvene and (-)-irofulven for use as antitumor agents1
• Bicycloundecadienones and bicyclodecadienones via carbonylative cycloaddition2
• Monoalkyldiazenes for allylic reduction3Reacts with di-Me phosphonate4
Packaging
1, 5 g in glass bottle
Description (简体中文)
Application
用于烯丙基置换反应和醇类还原反应的试剂,5也可用于烯丙基碳酸酯和乙烯基环氧化物的立体选择性温和还原反应。3
IPNBSH A Reagent for the Simple Reduction of AlcoholsReactant for synthesis of:
• (-)-Acylfulvene and (-)-irofulven for use as antitumor agents1
• Bicycloundecadienones and bicyclodecadienones via carbonylative cycloaddition2
• Monoalkyldiazenes for allylic reduction3Reacts with di-Me phosphonate4
包装
1, 5 g in glass bottle

REFERENCES