N-Isopropylidene-N′-2-nitrobenzenesulfonyl hydrazine

• Catalog No.: 687855
• CAS Number: 6655-27-2
• M. F.: C9H11N3O4S
• M. W.: 257.26634
• Purity: 97%

SYNONYMS

• Title: N-异亚丙基-N′-2-硝基苯磺酰肼
• IUPAC name: 2-nitro-N'-(propan-2-ylidene)benzene-1-sulfonohydrazide
• IUPAC Traditional name: 2-nitro-N'-(propan-2-ylidene)benzenesulfonohydrazide
• Synonyms: IPNBSH; Acetone 2-nitrobenzenesulfonylhydrazone; 2-(1-Methylethylidene)hydrazide-2-nitrobenzenesulfonic acid; Isopropylidenehydrazide o-nitro-benzenesulfonic acid; 异亚丙基肼邻硝基苯磺酸

DATABASE IDS

• MDL Number: MFCD09800525
• CAS Number: 6655-27-2

PROPERTIES

• Empirical Formula (Hill Notation): C9H11N3O4S
• Purity: 97%
• Melting Point: 131-135 °C
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Reagent for allylic transposition and reduction of alcohols,5 as well as mild and stereoselective reduction of allylic carbonates and vinyl epoxides.3
IPNBSH A Reagent for the Simple Reduction of AlcoholsReactant for synthesis of:
• (-)-Acylfulvene and (-)-irofulven for use as antitumor agents1
• Bicycloundecadienones and bicyclodecadienones via carbonylative cycloaddition2
• Monoalkyldiazenes for allylic reduction3Reacts with di-Me phosphonate4
Packaging
1, 5 g in glass bottle

Description (简体中文)

Application
用于烯丙基置换反应和醇类还原反应的试剂，5也可用于烯丙基碳酸酯和乙烯基环氧化物的立体选择性温和还原反应。3
IPNBSH A Reagent for the Simple Reduction of AlcoholsReactant for synthesis of:
• (-)-Acylfulvene and (-)-irofulven for use as antitumor agents1
• Bicycloundecadienones and bicyclodecadienones via carbonylative cycloaddition2
• Monoalkyldiazenes for allylic reduction3Reacts with di-Me phosphonate4
包装
1, 5 g in glass bottle