4-Nitrophenylboronic acid

• Catalog No.: 673854
• CAS Number: 24067-17-2
• M. F.: C6H6BNO4
• M. W.: 166.92714
• Purity: ≥95.0%

SYNONYMS

• Title: 4-硝基苯硼酸
• IUPAC name: (4-nitrophenyl)boronic acid
• IUPAC Traditional name: 4-nitrophenylboronic acid
• Synonyms: p-nitro-benzeneboronic acid; 4-Nitrobenzeneboronic acid; p-Nitrophenylboronic acid

DATABASE IDS

• MDL Number: MFCD00161360
• PubChem SID: 24885181
• CAS Number: 24067-17-2

PROPERTIES

• Linear Formula: (O2N)C6H4(B(OH)2)
• Purity: ≥95.0%
• Melting Point: 285-290 °C (dec.)
• GHS Signal Word: Warning
• GHS Hazard statements: H302
• European Hazard Symbols: Harmful (Xn)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• Risk Statements: 22
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
May contain varying amounts of anhydride
Packaging
1, 5 g in glass bottle
Application
Reagent used for
• Ligand-free palladium-catalyzed Suzuki-Miyaura cross-couplings1
• Ruthenium catalyzed direct arylation of benzylic sp3 carbons of acyclic amines2
• Diels-Alder or C-H activation reactions3
• Regioselective Suzuki-Miyaura coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulations4
• N-arylation of phenylurea using copper acetylacetonate catalyst5
• Environmentally benign one-pot synthesis through a double arylation process6
• Copper-mediated cyanations7
• copper-catalyzed arylations8
• Regioselective glycosylations9
• Suzuki couplings followed by arylations10
• X-ray absorption on rhodium-grafted hydrotalcite catalyst for heterogeneous 1,4-addition reaction of organoboron reagents to electron deficient olefins11 Reagent used in Preparation of
• Combretastatin analogs as potential antitumor agents12
• Human immunodeficiency virus (HIV) protease inhibitors with antiviral activities against drug-resistant viruses13

Description (简体中文)

Other Notes
可能含不定量的酸酐
包装
1, 5 g in glass bottle
Application
Reagent used for
• Ligand-free palladium-catalyzed Suzuki-Miyaura cross-couplings1
• Ruthenium catalyzed direct arylation of benzylic sp3 carbons of acyclic amines2
• Diels-Alder or C-H activation reactions3
• Regioselective Suzuki-Miyaura coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulations4
• N-arylation of phenylurea using copper acetylacetonate catalyst5
• Environmentally benign one-pot synthesis through a double arylation process6
• Copper-mediated cyanations7
• copper-catalyzed arylations8
• Regioselective glycosylations9
• Suzuki couplings followed by arylations10
• X-ray absorption on rhodium-grafted hydrotalcite catalyst for heterogeneous 1,4-addition reaction of organoboron reagents to electron deficient olefins11 Reagent used in Preparation of
• Combretastatin analogs as potential antitumor agents12
• Human immunodeficiency virus (HIV) protease inhibitors with antiviral activities against drug-resistant viruses13