Tris[4-(5-dicyanomethylidenemethyl-2-thienyl)phenyl]amine

• Catalog No.: 687251
• CAS Number: 883236-54-2
• M. F.: C42H21N7S3
• M. W.: 719.85804
• Purity: 97%

SYNONYMS

• Title: 三[4-(5-二氰基亚甲基甲基-2-噻吩基)苯基]胺
• IUPAC name: 2-[(5-{4-[bis({4-[5-(2,2-dicyanoeth-1-en-1-yl)thiophen-2-yl]phenyl})amino]phenyl}thiophen-2-yl)methylidene]propanedinitrile
• IUPAC Traditional name: 2-[(5-{4-[bis({4-[5-(2,2-dicyanoeth-1-en-1-yl)thiophen-2-yl]phenyl})amino]phenyl}thiophen-2-yl)methylidene]propanedinitrile
• Synonyms: TDCV-TPA

DATABASE IDS

• CAS Number: 883236-54-2
• MDL Number: MFCD09836233

PROPERTIES

• OPV Device Performance: ITO/PEDOT:PSS/TDCV-TPA/Al2• Short-circuit current density (Jsc): 1.7 mA/cm2• Open-circuit voltage (Voc): 0.76 V• Fill Factor (FF): 0.27• Power Conversion Efficiency (PCE): 0.4 %
• OPV Device Performance: ITO/PEDOT:PSS/TDCV-TPA/C60/LiF/AL2• Short-circuit current density (Jsc): 4.59 mA/cm2• Open-circuit voltage (Voc): 1.15 V• Fill Factor (FF): 0.28• Power Conversion Efficiency (PCE): 1.85 %
• OPV Device Performance: ITO/PEDOT:PSS/TDCV-TPA/PC61BM/Al3• Short-circuit current density (Jsc): 3.65 mA/cm2• Open-circuit voltage (Voc): 0.96 V• Fill Factor (FF): 0.29• Power Conversion Efficiency (PCE): 1.02 %
• Empirical Formula (Hill Notation): C42H21N7S3
• Purity: 97%
• Risk Statements: 36/37/38
• Safety Statements: 26
• German water hazard class: 3
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Fluorescence: λex 510 nm; λem 592 nm in chloroform
• Melting Point: 400 °C
• Orbital energy: HOMO 6 eV
• Orbital energy: LUMO 4.2 eV

DETAILS

Description (English)

Packaging
100 mg in glass bottle
Application
Isotropic organic semiconductor for OPV′s and OLED′s. TDCV-TPA1,2 is soluble in a large variety of organic solvents and can be used for the fabrication of heterojunction solar cells with high open-circuit voltage (1.15V), efficiency close to 2% and longer ambient condition lifetimes than cells based on poly(alkylthiophenes). The compound absorbs at 509nm (in CH2Cl2 solution) and 538nm as thin film. It can be used as high spectral purity luminophore in LED′s, emitting red light at 658nm.

Description (简体中文)

包装
100 mg in glass bottle
Application
用于 OPV 和 OLED 的各向同性有机半导体。TDCV-TPA1,2 可溶于多种有机溶剂，可用于制造具有高开路电压 (1.15V) 的异质结太阳能电池，效率接近 2%，并且环境条件寿命比聚烷基噻吩型电池更长。该化合物可作为薄膜在 509nm（CH2Cl2 溶液中）和 538nm 处吸光。可用作 LED 中的高光谱纯度发光体，在 658nm 处发出红光。