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Pentamethylcyclopentadienylrhodium(III) chloride dimer_Molecular_structure_CAS_12354-85-7)
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Pentamethylcyclopentadienylrhodium(III) chloride dimer

Catalog No. 686891 Name Sigma Aldrich
CAS Number 12354-85-7 Website http://www.sigmaaldrich.com
M. F. C20H30Cl4Rh2 Telephone 1-800-521-8956
M. W. 618.0752 Fax
Purity Email
Storage Chembase ID: 140457

SYNONYMS

Title
二氯(五甲基环戊二烯基)合铑(III)二聚体
IUPAC name
bis(dichlororhodiumylium); bis(pentamethylcyclopenta-2,4-dien-1-ide)
IUPAC Traditional name
bis(dichlororhodiumylium); bis(pentamethylcyclopenta-2,4-dien-1-ide)
Synonyms
1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex
Bis(pentamethylcyclopentadienylrhodium dichloride)
Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer
Bis(dichloro(pentamethylcyclopentadienyl)rhodium)
Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium

DATABASE IDS

CAS Number 12354-85-7
MDL Number MFCD00061552

PROPERTIES

Linear Formula [Rh(C5Me5)Cl2]2
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H302-H312-H315-H319-H332-H335
European Hazard Symbols Harmful Harmful (Xn)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P280-P305 + P351 + P338
Risk Statements 20/21/22-36/37/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Packaging
2 g in glass bottle
500 mg in glass bottle
Legal Information
A product of Umicore.
Application
Umicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for:
• Oxidative olefination reactions1
• C-C bond cleavage of secondary alcohols2
• Ortho C-H olefination of phenol derivatives3
• Oxidative annulation of pyridines4
• Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond5
• Amidation reactions6
• Reductive alkylation reactions7
Description (简体中文)
包装
2 g in glass bottle
500 mg in glass bottle
Legal Information
Umicore 制造。
Application
Umicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for:
• Oxidative olefination reactions1
• C-C bond cleavage of secondary alcohols2
• Ortho C-H olefination of phenol derivatives3
• Oxidative annulation of pyridines4
• Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond5
• Amidation reactions6
• Reductive alkylation reactions7

REFERENCES