Hydroxy[-(S)-BINAP]-rhodium(I) Dimer

• Catalog No.: 661007
• M. F.: C88H66O2P4Rh2
• M. W.: 1485.170484
• Purity: 90%

SYNONYMS

• Title: 羟基[-(S)-BINAP]-铑(I) 二聚体
• IUPAC name: bis(rhodiumol); bis({1-[2-(diphenylphosphanyl)naphthalen-1-yl]naphthalen-2-yl}diphenylphosphane)
• IUPAC Traditional name: bis(binap); bis(rhodiumol)

DATABASE IDS

• PubChem SID: 24884495
• MDL Number: MFCD08561132

PROPERTIES

• Empirical Formula (Hill Notation): C88H66O2P4Rh2
• Impurities: 3-5% THF
• Impurities: 3-5% ethanol
• Purity: 90%
• German water hazard class: 3

DETAILS

Description (English)

Application
Catalyst employed in an asymmetric 1,6-addition of arylzinc reagents to dienones leading to chiral 5-substituted enones.1 Also used in an asymmetric 1,4-addition of organoboron reagents to cyclic and acyclic α,β-unsaturated ketones with excellent enantioselectivity.2
Efficient and Selective Catalysts for Asymmetric Synthesis
Packaging
1 g in glass bottle
250 mg in glass bottle

Description (简体中文)

Application
催化剂，用于芳基锌试剂不对称 1,6-加成到二烯酮，生成手性 5-取代烯酮。1还用于有机硼试剂不对称 1,4-加成到具有高对映选择性的环及非环 α,β-不饱和酮。2
Efficient and Selective Catalysts for Asymmetric Synthesis
包装
1 g in glass bottle
250 mg in glass bottle