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(S)-(-)-2,2′,6,6′-Tetramethoxy-4,4′-bis[di(3,5-xylyl)phosphino]-3,3′-bipyridine_Molecular_structure_CAS_443347-10-2)
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(S)-(-)-2,2′,6,6′-Tetramethoxy-4,4′-bis[di(3,5-xylyl)phosphino]-3,3′-bipyridine

Catalog No. 675946 Name Sigma Aldrich
CAS Number 443347-10-2 Website http://www.sigmaaldrich.com
M. F. C46H50N2O4P2 Telephone 1-800-521-8956
M. W. 756.847722 Fax
Purity 97% Email
Storage Chembase ID: 140318

SYNONYMS

Title
(S)-(-)-2,2′,6,6′-四甲氧基-4,4′-双(二(3,5-二甲苯基)膦-3,3′-联吡啶
IUPAC name
4-[bis(3,5-dimethylphenyl)phosphanyl]-3-{4-[bis(3,5-dimethylphenyl)phosphanyl]-2,6-dimethoxypyridin-3-yl}-2,6-dimethoxypyridine
IUPAC Traditional name
4-[bis(3,5-dimethylphenyl)phosphanyl]-3-{4-[bis(3,5-dimethylphenyl)phosphanyl]-2,6-dimethoxypyridin-3-yl}-2,6-dimethoxypyridine
Synonyms
(S)-Xylyl-P-Phos

DATABASE IDS

PubChem SID 24885310
CAS Number 443347-10-2
MDL Number MFCD04974235

PROPERTIES

Empirical Formula (Hill Notation) C46H50N2O4P2
Purity 97%
Melting Point 158-162 °C
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Application
Ligand employed in the asymmetic hydrogenation of β-keto esters, 2-arylacrylates, aryl ketones , and other substrates.1
Packaging
100, 500 mg in glass bottle
Legal Information
Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US5886182 and any patents arising therefrom apply.
Description (简体中文)
Application
用于 β-酮酯、2-芳基丙烯酸酯、芳基酮和其他底物不对称加氢的配体。1
包装
100, 500 mg in glass bottle
Legal Information
与 Johnson Matthey Catalyst 联合销售,仅供研究使用。适用美国专利 US5886182 以及由此产生的任何专利。

REFERENCES