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Dichloro[1,3-Bis(2-methylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II)_Molecular_structure_CAS_927429-60-5)
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Dichloro[1,3-Bis(2-methylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II)

Catalog No. 682284 Name Sigma Aldrich
CAS Number 927429-60-5 Website http://www.sigmaaldrich.com
M. F. C42H58Cl2N2PRu Telephone 1-800-521-8956
M. W. 793.873081 Fax
Purity Email
Storage Chembase ID: 140391

SYNONYMS

Title
二氯[1,3-双(2-甲基苯基)-2-咪唑烷亚基](亚苄基)(三环己基膦)钌(II)
IUPAC name
[1,3-bis(2-methylphenyl)imidazolidin-2-yl]dichloro(phenylmethylidene)ruthenium; tricyclohexylphosphane
IUPAC Traditional name
[1,3-bis(2-methylphenyl)imidazolidin-2-yl]dichloro(phenylmethylidene)ruthenium; tricyclohexylphosphine
Synonyms
[1,3-双(2-甲基苯基)-2-咪唑烷亚基]二氯(苯基亚甲基)(三环己基膦)钌(II)
[1,3-Bis(2-methylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene) (tricyclohexylphosphine)ruthenium(II)

DATABASE IDS

CAS Number 927429-60-5
PubChem SID 24885689

PROPERTIES

Empirical Formula (Hill Notation) C42H57Cl2N2PRu
Melting Point 160.5-161.0 °C
GHS Pictograms GHS02
GHS Signal Word Warning
GHS Hazard statements H228
European Hazard Symbols Flammable Flammable (F)
MSDS Link Download
GHS Precautionary statements P210
Risk Statements 11
Storage Temperature 2-8°C
German water hazard class 3

DETAILS

Description (English)
Application
Metathesis: Ruthenium-Based Metathesis Catalysts

• Highly reactive in metathesis of sterically hindered olefins, particularly in Ring-Closing Metathesis (RCM).
• Useful for the preparation of tetrasubstituted olefins via RCM.1,2
• Enabling metathesis catalyst.1
Other Notes
NO BULK ORDERS
Packaging
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
Sale of this product conveys to the buyer a limited-use research license. For full details of this license please see sigma-aldrich.com/materialicense. For questions, please contact us at aldrich@sial.com or Materia at info@materia-inc.com.
Description (简体中文)
Application
Metathesis: Ruthenium-Based Metathesis Catalysts
有效的复分解催化剂。1
Other Notes
不接受大宗订购
包装
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
美国专利 6,111,121 和 7,329,758(以及上述专利的相关国外等同专利)均适用。销售该产品可向购买者转让限制使用研究许可。有关该许可的完整详细内容,请访问 sigma-aldrich.com/materialicense。如有疑问,请发送邮件至 aldrich@sial.com 与我们联系,或发送至 info@materia-inc.com 联系 Materia。

REFERENCES