2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine

• Catalog No.: 673986
• CAS Number: 357209-32-6
• M. F.: C25H19N3O2
• M. W.: 393.43726
• Purity: ≥94%

SYNONYMS

• Title: 2,6-双[(3aR,8aS)-(+)-8H-茚并[1,2-d]噁唑啉-2-基)吡啶
• IUPAC name: 2,6-bis[(3aR,8aS)-3aH,8H,8aH-indeno[1,2-d][1,3]oxazol-2-yl]pyridine
• IUPAC Traditional name: 2,6-bis[(3aR,8aS)-3aH,8H,8aH-indeno[1,2-d][1,3]oxazol-2-yl]pyridine
• Synonyms: (3aR,3′aR,8aS,8′aS)-2,2′-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole; (3aR,8aS)-in-pybox; (3aR,3′aR,8aS,8′aS)-2,2′-(2,6-吡啶二基)双[3a,8a-二氢-8H-茚并[1,2-d]噁唑

DATABASE IDS

• PubChem SID: 24885191
• CAS Number: 357209-32-6
• MDL Number: MFCD09265074

PROPERTIES

• Empirical Formula (Hill Notation): C25H19N3O2
• Purity: ≥94%
• Melting Point: 284 °C (dec.)
• Optical Rotation: [α]20/D +386°, c = 1 in methylene chloride(lit.)
• GHS Hazard statements: H413
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1 g in glass bottle
250 mg in glass bottle
Application
Catalytic ligand used for:
• [3+2] cycloaddition of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage1
• Enantioselective Mukaiyama-aldol reactions2
• Enantioselective carbonyl-ene reactions3
• Cu(I)-catalyzed asymmetric alkynylation of imino esters with terminal alkynes4
• Asymmetric three-component coupling reactions catalyzed by a Cu/pybox complex5
• Enantioselective Diels-Alder reaction6
• Ni-catalyzed cross-coupling reactions7

Description (简体中文)

包装
1 g in glass bottle
250 mg in glass bottle
Application
Catalytic ligand used for:
• [3+2] cycloaddition of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage1
• Enantioselective Mukaiyama-aldol reactions2
• Enantioselective carbonyl-ene reactions3
• Cu(I)-catalyzed asymmetric alkynylation of imino esters with terminal alkynes4
• Asymmetric three-component coupling reactions catalyzed by a Cu/pybox complex5
• Enantioselective Diels-Alder reaction6
• Ni-catalyzed cross-coupling reactions7