2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine

• Catalog No.: 673978
• CAS Number: 185346-09-2
• M. F.: C25H19N3O2
• M. W.: 393.43726

SYNONYMS

• Title: 2,6-双[(3aS,8aR)-3a,8a-二氢-8H-茚并[1,2-d]噁唑啉-2-基]吡啶
• IUPAC name: 2,6-bis[(3aS,8aR)-3aH,8H,8aH-indeno[1,2-d][1,3]oxazol-2-yl]pyridine
• IUPAC Traditional name: 2,6-bis[(3aS,8aR)-3aH,8H,8aH-indeno[1,2-d][1,3]oxazol-2-yl]pyridine
• Synonyms: (3aS,8aR)-in-pybox; (3aS,3′aS,8aR,8′aR)-2,2′-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole; (3aS,3′aS,8aR,8′aR)-2,2′-(2,6-吡啶二基)双[3a,8a-二氢-8H-茚并[1,2-d]噁唑; Dimethlyammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2′-bis(dip-tolylphosphino)1,1′-binaphthyl]diruthenate(ΙΙ)

DATABASE IDS

• MDL Number: MFCD05861599
• CAS Number: 185346-09-2

PROPERTIES

• Empirical Formula (Hill Notation): C25H19N3O2
• Melting Point: 276-281 °C
• Optical Rotation: [α]20/D -375°, c = 1 in dichloromethane (typical)
• GHS Hazard statements: H413
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1 g in glass bottle
250 mg in glass bottle
Application
Reactant involved in synthesis of:
• Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts1
• Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles2
• Chiral N,N,N-tridentate pybos and pyboxazine ligands3

Description (简体中文)

包装
1 g in glass bottle
250 mg in glass bottle
Application
Reactant involved in synthesis of:
• Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts1
• Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles2
• Chiral N,N,N-tridentate pybos and pyboxazine ligands3