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Tris(4-chlorophenyl)phosphine

Catalog No. 249491 Name Sigma Aldrich
CAS Number 1159-54-2 Website http://www.sigmaaldrich.com
M. F. C18H12Cl3P Telephone 1-800-521-8956
M. W. 365.620641 Fax
Purity 95% Email
Storage Chembase ID: 82993

SYNONYMS

Title
三(4-氯苯基)膦
IUPAC name
tris(4-chlorophenyl)phosphane
IUPAC Traditional name
tris(4-chlorophenyl)phosphane
Synonyms
Tris(p-chlorophenyl)phosphine
NSC 136459

DATABASE IDS

EC Number 214-596-7
CAS Number 1159-54-2
MDL Number MFCD00013639
PubChem SID 24854999

PROPERTIES

Linear Formula (ClC6H4)3P
Purity 95%
Melting Point 100-103 °C(lit.)
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-37/39
German water hazard class 3

DETAILS

Description (English)
Packaging
1 g in glass bottle
Application
Catalyst for:
• Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes1
• Solvent-free Heck reactions2Cocatalyst in:
• Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents3
• Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes4
• Rhodium-catalyzed hydrogenation reactions5
• Platinum-catalyzed allylation reactions6
Description (简体中文)
包装
1 g in glass bottle
Application
Catalyst for:
• Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes1
• Solvent-free Heck reactions2Cocatalyst in:
• Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents3
• Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes4
• Rhodium-catalyzed hydrogenation reactions5
• Platinum-catalyzed allylation reactions6

REFERENCES