(1S)-(+)-3-Carene

• Catalog No.: 441619
• CAS Number: 498-15-7
• M. F.: C10H16
• M. W.: 136.23404
• Purity: 99%

SYNONYMS

• Title: (1S)-(+)-3-蒈烯
• IUPAC name: (1S,6R)-3,7,7-trimethylbicyclo[4.1.0]hept-3-ene
• IUPAC Traditional name: (+)-delta(3)-carene
• Synonyms: (+)-3-Carene; (1S)-3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene; (1S)-3,7,7-三甲基双环[4.1.0]庚-3-烯; (+)-3-蒈烯

DATABASE IDS

• PubChem SID: 24867688
• Beilstein Number: 1902767
• EC Number: 207-856-6
• CAS Number: 498-15-7
• MDL Number: MFCD00066417

PROPERTIES

• Empirical Formula (Hill Notation): C10H16
• Purity: 99%
• Boiling Point: 170-172 °C(lit.)
• Density: 0.865 g/mL at 25 °C(lit.)
• Flash Point: 55 °C
• Flash Point: 131 °F
• Optical Rotation: [α]20/D +17°, neat
• Refractive Index: n20/D 1.472(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H226-H317-H410
• European Hazard Symbols: Irritant (Xi)
• European Hazard Symbols: Nature polluting (N)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P273-P280-P501
• RID/ADR: UN 2319 3/PG 3
• Risk Statements: 10-43-50/53
• Safety Statements: 36/37-60-61
• Hazard Class: 3
• UN Number: 2319
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1, 5 g in glass bottle
Application
Chiral building block for the preparation of bicyclo[3.2.0]heptenes that are useful intermediates in the synthesis of (+)-lineatin and both enantiomers of capnellene.1 Has been converted to its corresponding allenyl allylic ether2 for studies of its thermal isomerization chemistry. Precursor to di(4-isocaranyl)borane, an asymmetric hydroboration reagent for olefins.3

Description (简体中文)

包装
1, 5 g in glass bottle
Application
用于制备二环[3.2.0]庚烯的手性结构单元，二环[3.2.0]庚烯是合成 (+)-三甲基二氧三环壬烷和三并五元环倍半萜两个对映体的中间体。1可转化为对应的联烯基烯丙基醚2，用于研究其热异构化作用。二(4-异蒈烷基)硼烷的前体，是烯烃不对称硼氢化反应的试剂。3