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4-Formylphenylboronic acid_Molecular_structure_CAS_87199-17-5)
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4-Formylphenylboronic acid

Catalog No. 431966 Name Sigma Aldrich
CAS Number 87199-17-5 Website http://www.sigmaaldrich.com
M. F. C7H7BO3 Telephone 1-800-521-8956
M. W. 149.93968 Fax
Purity ≥95.0% Email
Storage Chembase ID: 8355

SYNONYMS

Title
4-甲酰基苯硼酸
IUPAC name
(4-formylphenyl)boronic acid
IUPAC Traditional name
4-formylphenylboronic acid
Synonyms
4-Boronobenzaldehyde
4-(Dihydroxyboryl)benzaldehyde
对甲酰苯硼酸
4-Formylbenzeneboronic acid
p-Formylbenzeneboronic acid
p-Formylphenylboronic acid
4-醛基苯硼酸

DATABASE IDS

PubChem SID 24867058
Beilstein Number 3030770
CAS Number 87199-17-5
MDL Number MFCD00151823

PROPERTIES

GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H314-H317
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 1759 8/PG 3
Risk Statements 34
Safety Statements 22-26-36/37/39-45
Hazard Class 8
UN Number 1759
Packing Group 3
German water hazard class 3
GHS Pictograms GHS05
Linear Formula HCOC6H4B(OH)2
Purity ≥95.0%
Melting Point 237-242 °C(lit.)

DETAILS

Description (简体中文)
Other Notes
含不定量的酸酐
包装
1, 5, 25 g in glass bottle
Application
Reagent used for
• Palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water1
• Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides2
• Ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids3
• Triethylamine-catalyzed three-component Hantzsch condensations4
• Copper-catalyzed nitrations5
• Oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta6
• Palladacycle-catalyzed cross-coupling of arylboronic acids with carboxylic anhydrides or acyl chlorides7
• Palladium-catalyzed aerobic oxidative cross-coupling reactions8 Reagent used in Preparation of
• Sensitizers with dithiafulvenyl unit as electron donor for high-efficiency dye-sensitized solar cells9
• A novel protein synthesis inhibitor active against Gram-positive bacteria10
Description (English)
Other Notes
Contains varying amounts of anhydride
Packaging
1, 5, 25 g in glass bottle
Application
Reagent used for
• Palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water1
• Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides2
• Ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids3
• Triethylamine-catalyzed three-component Hantzsch condensations4
• Copper-catalyzed nitrations5
• Oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta6
• Palladacycle-catalyzed cross-coupling of arylboronic acids with carboxylic anhydrides or acyl chlorides7
• Palladium-catalyzed aerobic oxidative cross-coupling reactions8 Reagent used in Preparation of
• Sensitizers with dithiafulvenyl unit as electron donor for high-efficiency dye-sensitized solar cells9
• A novel protein synthesis inhibitor active against Gram-positive bacteria10

REFERENCES