(S)-BINAPINE-rhodium complex

• Catalog No.: 659622
• CAS Number: 1046806-02-3
• M. F.: C60H60BF4P2Rh
• M. W.: 1032.7760348

SYNONYMS

• Title: (S)-二叔丁基四氢联二萘磷-铑配合物
• IUPAC name: λ^1-rhodium(1+) ion (12R)-13-tert-butyl-12-[(12R)-13-tert-butyl-13-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-12-yl]-13-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaene cycloocta-1,5-diene tetrafluoroboranuide
• IUPAC Traditional name: λ^1-rhodium(1+) ion (12R)-13-tert-butyl-12-[(12R)-13-tert-butyl-13-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-12-yl]-13-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaene 1,5-cyclooctadiene tetrafluoroborate
• Synonyms: [(S)-二叔丁基四氢联二萘磷(环辛二烯)铑(I)]四氟硼酸盐; [(S)-BINAPINE(cyclooctadiene)rhodium(I)] tetrafluoroborate

DATABASE IDS

• PubChem SID: 24884435
• CAS Number: 1046806-02-3
• MDL Number: MFCD07782007

PROPERTIES

• Empirical Formula (Hill Notation): C60H60BF4P2Rh
• Melting Point: >300 °C
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Demonstates excellent enantioselectivity and reactivity for the asymmetric hydrogenation of Z-β-aryl(β-acylamino)acrylates.1
Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
Packaging
100, 500 mg in glass bottle

Description (简体中文)

Application
用于 Z-β-芳基(β-酰氨基)丙烯酸酯的不对称氢化反应中具有优异的对映选择性和反应性。1
Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
包装
100, 500 mg in glass bottle