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(S)-(-)-2,2′,6,6′-Tetramethoxy-4,4′-bis(diphenylphosphino)-3,3′-bipyridine_Molecular_structure_CAS_362524-23-0)
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(S)-(-)-2,2′,6,6′-Tetramethoxy-4,4′-bis(diphenylphosphino)-3,3′-bipyridine

Catalog No. 675792 Name Sigma Aldrich
CAS Number 362524-23-0 Website http://www.sigmaaldrich.com
M. F. C38H34N2O4P2 Telephone 1-800-521-8956
M. W. 644.635082 Fax
Purity 97% Email
Storage Chembase ID: 140154

SYNONYMS

Title
(S)-(-)-2,2′,6,6′-四甲氧基-4,4′-双(二苯基膦)-3,3′-联吡啶
IUPAC name
4-(diphenylphosphanyl)-3-[4-(diphenylphosphanyl)-2,6-dimethoxypyridin-3-yl]-2,6-dimethoxypyridine
IUPAC Traditional name
4-(diphenylphosphanyl)-3-[4-(diphenylphosphanyl)-2,6-dimethoxypyridin-3-yl]-2,6-dimethoxypyridine
Synonyms
(S)-P-Phos

DATABASE IDS

CAS Number 362524-23-0
PubChem SID 24885300
MDL Number MFCD04038734

PROPERTIES

Empirical Formula (Hill Notation) C38H34N2O4P2
Purity 97%
Melting Point 261-265 °C
Optical Rotation [α]20/D -98°, c = 1 in chloroform
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Risk Statements 37
German water hazard class 3

DETAILS

Description (English)
Application
Ligand employed in the asymmetic hydrogenation of β-keto esters, 2-arylacrylates, aryl ketones , and other substrates.1
Packaging
100, 500 mg in glass bottle
Legal Information
Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US5886182 and any patents arising therefrom apply.
Description (简体中文)
Application
用于 β-酮酯、2-芳基丙烯酸酯、芳基酮和其他底物不对称加氢的配体。1
包装
100, 500 mg in glass bottle
Legal Information
与 Johnson Matthey Catalyst 联合销售,仅供研究使用。适用美国专利 US5886182 以及由此产生的任何专利。

REFERENCES