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1,2,3,4,5-Pentaphenyl-1′-(di-tert-butylphosphino)ferrocene_Molecular_structure_CAS_312959-24-3)
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1,2,3,4,5-Pentaphenyl-1′-(di-tert-butylphosphino)ferrocene

Catalog No. 675784 Name Sigma Aldrich
CAS Number 312959-24-3 Website http://www.sigmaaldrich.com
M. F. C48H47FeP Telephone 1-800-521-8956
M. W. 710.705541 Fax
Purity Email
Storage Chembase ID: 140153

SYNONYMS

Title
1,2,3,4,5-戊苯基-1′-(二叔丁基磷基)二茂铁
IUPAC name
λ2-iron(2+) ion 3-(di-tert-butylphosphanyl)cyclopenta-2,4-dien-1-ide pentaphenylcyclopenta-2,4-dien-1-ide
IUPAC Traditional name
λ2-iron(2+) ion 3-(di-tert-butylphosphanyl)cyclopenta-2,4-dien-1-ide pentaphenylcyclopenta-2,4-dien-1-ide
Synonyms
Q-Phos
QPhos

DATABASE IDS

PubChem SID 24885299
CAS Number 312959-24-3
MDL Number MFCD03788940

PROPERTIES

Linear Formula [(C6H5)5C5]Fe[C5H4(P(C4H9)2)]
Ligand For Arylations
Ligand For Buchwald-Hartwig Cross Coupling Reaction
Ligand For Sonogashira Coupling
Ligand For Suzuki-Miyaura Coupling
Melting Point 211-219 °C
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26
German water hazard class 3

DETAILS

Description (English)
Application
Sterically hindered phosphine with broad application in a variety of palladium-catalyzed amination and etherification reactions of aryl chlorides.1
Packaging
100, 500 mg in glass bottle
Legal Information
Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US6562989 B2 and any patents arising therefrom apply.
Description (简体中文)
Application
具有空间位阻的膦,广泛用于芳基氯的各种钯催化胺化和醚化反应。1
包装
100, 500 mg in glass bottle
Legal Information
与 Johnson Matthey Catalyst 合作销售,仅供研究使用。适用美国专利 US6562989 B2 以及由此产生的专利。

REFERENCES