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Tetrakis(dimethylamino)ethylene_Molecular_structure_CAS_996-70-3)
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Tetrakis(dimethylamino)ethylene

Catalog No. 674613 Name Sigma Aldrich
CAS Number 996-70-3 Website http://www.sigmaaldrich.com
M. F. C10H24N4 Telephone 1-800-521-8956
M. W. 200.32436 Fax
Purity Email
Storage Chembase ID: 140149

SYNONYMS

Title
四(二甲氨基)乙烯
IUPAC name
dimethyl[tris(dimethylamino)ethenyl]amine
IUPAC Traditional name
dimethyl[tris(dimethylamino)ethenyl]amine
Synonyms
TDAE
Octamethylethylenetetramine
四(乙氨基)乙烯

DATABASE IDS

Beilstein Number 1705900
CAS Number 996-70-3
MDL Number MFCD00009601
EC Number 213-638-1
PubChem SID 24885226

PROPERTIES

Linear Formula [(CH3)2N]2C=C[N(CH3)2]2
Boiling Point 59 °C/0.9 mmHg(lit.)
Density 0.861 g/mL at 25 °C(lit.)
Flash Point 53 °C
Flash Point 127.4 °F
Refractive Index n20/D 1.48(lit.)
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H226-H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 2734 8/PG 2
Risk Statements 10-34
Safety Statements 26-36/37/39-45
Hazard Class 8
UN Number 2734
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Application
Reagent used to convert α-bromoketones into 1,4-diketones.8
Involved in TDAE methodology1 for coupling and intramolecular Buchwald reactions2Acts as a reducing agent3,4Reactant involved in:
• Dioxygenation5
• Insertion of aluminum anion into the C-N bond6
• Chemiluminescent reactions with oxygen7
Packaging
1, 10, 50 g in glass bottle
Description (简体中文)
Application
用于将 α-溴代酮类化合物转化成 1,4-二酮类化合物。8
Involved in TDAE methodology1 for coupling and intramolecular Buchwald reactions2Acts as a reducing agent3,4Reactant involved in:
• Dioxygenation5
• Insertion of aluminum anion into the C-N bond6
• Chemiluminescent reactions with oxygen7
包装
1, 10, 50 g in glass bottle

REFERENCES