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1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)_Molecular_structure_CAS_104439-77-2)
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1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)

Catalog No. 668281 Name Sigma Aldrich
CAS Number 104439-77-2 Website http://www.sigmaaldrich.com
M. F. C62H41O6Ru2 Telephone 1-800-521-8956
M. W. 1084.12534 Fax
Purity 98% Email
Storage Chembase ID: 140147

SYNONYMS

Title
1-羟基四苯基-环戊二烯基(四苯基-2,4-环戊二烯-1-酮)-μ-氢四羰基二钌(II)
IUPAC name
2-hydroxy-1,3,4,5-tetraphenylcyclopenta-2,4-dien-1-ide; dirutheniumylium; tetrakis(methanidylidyneoxidanium); tetraphenylcyclopenta-2,4-dien-1-one
IUPAC Traditional name
2-hydroxy-1,3,4,5-tetraphenylcyclopenta-2,4-dien-1-ide; tetrakis(carbon monoxide); dirutheniumylium; tetraphenylcyclopentadienone
Synonyms
Shvo 催化剂
Tetracarbonyl-μ-hydro[(1,2,3,4,5-H)-1-hydroxylato-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl][(1,2,3,4,5-H)-1-hydroxy-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl]diruthenium
Shvo’s Catalyst
2,4-环戊二烯-1-酮 2,3,4,5-四苯基钌络合物
2,4-Cyclopentadien-1-one, 2,3,4,5-tetraphenyl-, ruthenium complex
四羰基-μ-氢[(1,2,3,4,5-H)-1-羟基-2,3,4,5-四苯基-2,4-环戊二烯-1-yl][(1,2,3,4,5-H)-1-羟基-2,3,4,5-四苯基-2,4-环戊二烯-1-基]二钌

DATABASE IDS

PubChem SID 24884974
CAS Number 104439-77-2

PROPERTIES

Empirical Formula (Hill Notation) C62H42O6Ru2
Purity 98%
Melting Point 223-227 °C
MSDS Link Download
German water hazard class 3

DETAILS

Description (English)
Application
Has found numerous applications as a versatile catalyst in organic synthesis, including the reduction of aldehydes and ketones to alcohols, bimolecular disproportionation reaction of aldehydes to esters, isomerization of allylic alcohols and oxidation of alcohols.1,2
Shvo’s Catalyst
Packaging
100, 500 mg in glass bottle
Description (简体中文)
Application
已发现多种用途,如作为有机合成的多功能催化剂,有机合成反应包括醛和酮的还原反应生成醇,醛的双分子歧化反应生成酯,烯丙醇的异构化反应以及醇的氧化反应。1,2
Shvo’s Catalyst
包装
100, 500 mg in glass bottle

REFERENCES