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Propargyl bromide solution_Molecular_structure_CAS_106-96-7)
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Propargyl bromide solution

Catalog No. P51001 Name Sigma Aldrich
CAS Number 106-96-7 Website http://www.sigmaaldrich.com
M. F. C3H3Br Telephone 1-800-521-8956
M. W. 118.95992 Fax
Purity Email
Storage Chembase ID: 73508

SYNONYMS

Title
炔丙基溴 溶液
IUPAC name
3-bromoprop-1-yne
IUPAC Traditional name
1-propyne, 3-bromo-
Synonyms
3-Bromo-1-propyne
3-溴-1-丙炔

DATABASE IDS

PubChem SID 24898595
MDL Number MFCD00000241
CAS Number 106-96-7
Beilstein Number 605309

PROPERTIES

Concentration 80 wt. % in toluene
Contains 0.3% magnesium oxide as stabilizer
Linear Formula HC≡CCH2Br
Boiling Point 88-90 °C
Density 1.335 g/mL at 25 °C
Flash Point 18 °C
Flash Point 64.4 °F
Refractive Index n20/D 1.494
GHS Pictograms GHS02
GHS Pictograms GHS06
GHS Pictograms GHS08
GHS Signal Word Danger
GHS Hazard statements H225-H301-H304-H315-H319-H335-H336-H361d-H373
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Toxic Toxic (T)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P261-P281-P301 + P310-P305 + P351 + P338-P331
RID/ADR UN 2345 3/PG 2
Risk Statements 63-11-25-36/37/38-48/20-65-67
Safety Statements 16-26-36/37-45-62
Storage Temperature 2-8°C
Hazard Class 3
UN Number 2345
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Packaging
5, 25 kg in steel drum
50, 125, 625 g in Sure/Seal™
Application
Used to make propargylic amines employed in enyne metathesis.1Employed in the propargylation of spiro ketones,2 allylic alcohols,3 and enone complexes.4
Description (简体中文)
包装
5, 25 kg in steel drum
50, 125, 625 g in Sure/Seal™
Application
用于制备烯炔复分解反应中所用的丙炔酸胺。1 用于螺酮2、烯丙醇3和烯酮复合物的炔丙基化反应。4

REFERENCES