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tert-Butyl hydroperoxide solution_Molecular_structure_CAS_75-91-2)
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tert-Butyl hydroperoxide solution

Catalog No. 418064 Name Sigma Aldrich
CAS Number 75-91-2 Website http://www.sigmaaldrich.com
M. F. C4H10O2 Telephone 1-800-521-8956
M. W. 90.121 Fax
Purity Email
Storage Chembase ID: 105404

SYNONYMS

Title
叔丁基过氧化氢 溶液
IUPAC name
2-methylpropane-2-peroxol
IUPAC Traditional name
tert-butyl hydroperoxide
Synonyms
2-Hydroperoxy-2-methylpropane
TBHP
1,1-Dimethylethyl hydroperoxide

DATABASE IDS

Beilstein Number 1098280
PubChem SID 24866199
CAS Number 75-91-2
MDL Number MFCD00002130

PROPERTIES

Concentration 5.0-6.0 M in nonane
Impurities <4% water
Linear Formula (CH3)3COOH
Density 0.817 g/mL at 25 °C
Flash Point 29 °C
Flash Point 84.2 °F
Refractive Index n20/D 1.399
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS06
GHS Pictograms GHS08
GHS Pictograms GHS09
GHS Signal Word Danger
GHS Hazard statements H226-H242-H302-H304-H311 + H331-H314-H317-H336-H341-H411
European Hazard Symbols Oxidising Oxidising (O)
European Hazard Symbols Toxic Toxic (T)
European Hazard Symbols Nature polluting Nature polluting (N)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P220-P261-P273-P280-P301 + P310-P305 + P351 + P338
RID/ADR UN 3105 5.2
Risk Statements 7-10-21/22-23-34-43-51/53-65-68
Safety Statements 3/7-14-26-36/37/39-45-61-62
Storage Temperature 2-8°C
Hazard Class 5.2
UN Number 3105
German water hazard class 3

DETAILS

Description (English)
Packaging
50 mL in poly bottle
Protocols & Applications
Asymmetric Epoxidation of Allylic Alcohols
Asymmetric Epoxidation of Homoallylic Alcohols
Asymmetric Ketone Hydrogenation
Asymmetric Transfer Hydrogenation
Description (简体中文)
包装
50 mL in poly bottle
Protocols & Applications
Asymmetric Epoxidation of Allylic Alcohols
Asymmetric Epoxidation of Homoallylic Alcohols
Asymmetric Ketone Hydrogenation
Asymmetric Transfer Hydrogenation

REFERENCES