(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)piperidine

• Catalog No.: 665479
• M. F.: C25H42NO2P
• M. W.: 419.580241
• Purity: 97%

SYNONYMS

• Title: (S)-(+)-(3,5-二氧杂-4-磷杂环庚二烯并[2,1-a:3,4-a′]二萘-4-基)哌啶
• IUPAC name: 1-{12,14-dioxa-13-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosan-13-yl}piperidine
• IUPAC Traditional name: 1-{12,14-dioxa-13-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosan-13-yl}piperidine
• Synonyms: (S)-(+)-4-二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英-4-基-哌啶; (S)-(+)-4-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-piperidine; (S)-PipPhos

DATABASE IDS

• MDL Number: MFCD08276865
• PubChem SID: 24884739

PROPERTIES

• Empirical Formula (Hill Notation): C25H22NO2P
• Purity: 97%
• Melting Point: 206-213 °C
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Asymmetric hydrogenation of N-aryl imines1
Phosphoramidite ligand used in a rhodium-catalyzed enantioselective 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds.
DSM MonoPhos Family of Highly Efficient Privileged Ligands
Packaging
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
Sold under license from DSM for research purposes only.

Description (简体中文)

Application
N-芳基亚胺的不对称氢化反应1
亚磷酰胺配体，用于芳基硼酸经铑催化的不对称 1,4-加成反应，加成到 α,β-不饱和羰基化合物。
DSM MonoPhos Family of Highly Efficient Privileged Ligands
包装
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
经 DSM 授权销售，仅供研究使用。