(3aR,8aR)-(-)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine

• Catalog No.: 665460
• CAS Number: 213843-90-4
• M. F.: C33H34NO4P
• M. W.: 539.601121
• Purity: 96%

SYNONYMS

• Title: (3aR,8aR)-(-)-(2,2-二甲基-4,4,8,8-四苯基-四氢-[1,3]二噁唑并[4,5-e][1,3,2]二噁磷杂庚英-6-基)二甲基胺
• IUPAC name: (3aR,8aR)-N,N,2,2-tetramethyl-4,4,8,8-tetraphenyl-hexahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-amine
• IUPAC Traditional name: (3aR,8aR)-N,N,2,2-tetramethyl-4,4,8,8-tetraphenyl-dihydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-amine

DATABASE IDS

• PubChem SID: 24884738
• CAS Number: 213843-90-4
• MDL Number: MFCD04117685

PROPERTIES

• Empirical Formula (Hill Notation): C33H34NO4P
• Purity: 96%
• Melting Point: 218-221 °C
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Phosphoramidite ligand employed in an asymmetric, iridium-catalyzed, allylic allylation of propenylboronates.1 Also used in a copper-catalyzed asymmetric conjugate addition of diethylzinc to α,β-unsaturated imines derived from amino acids.2
DSM MonoPhos Family of Highly Efficient Privileged Ligands
Packaging
100, 500 mg in glass bottle
Legal Information
Sold under license from DSM for research purposes only.

Description (简体中文)

Application
亚磷酰胺配体，用于丙烯基硼酸酯的铱催化不对称烯丙基化反应。1还用于二乙基锌的铜催化不对称共轭加成至氨基酸衍生的 α,β-不饱和亚胺。2
DSM MonoPhos Family of Highly Efficient Privileged Ligands
包装
100, 500 mg in glass bottle
Legal Information
经 DSM 授权销售，仅供研究之用。