(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

• Catalog No.: 404438
• CAS Number: 135616-36-3
• M. F.: C36H54N2O2
• M. W.: 546.82616
• Purity: 98%

SYNONYMS

• Title: (S,S)-(+)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺
• IUPAC name: 2,4-di-tert-butyl-6-{N-[(1S,2S)-2-{[(3,5-di-tert-butyl-2-hydroxyphenyl)methylidene]amino}cyclohexyl]carboximidoyl}phenol
• IUPAC Traditional name: 2,4-di-tert-butyl-6-{N-[(1S,2S)-2-{[(3,5-di-tert-butyl-2-hydroxyphenyl)methylidene]amino}cyclohexyl]carboximidoyl}phenol
• Synonyms: (S,S)-Jacobsen’s ligand; (S,S)-Jacobsen 配体

DATABASE IDS

• MDL Number: MFCD00191801
• Beilstein Number: 5464823
• CAS Number: 135616-36-3
• PubChem SID: 24865245

PROPERTIES

• Linear Formula: [[(CH3)3C]2C6H2-2-(OH)CH=N]2C6H10
• Purity: 98%
• Melting Point: 203-206 °C(lit.)
• Optical Rotation: [α]20/D +315 to 15°, c = 1 in methylene chloride
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1, 5 g in glass bottle
Legal Information
Licensed through Research Corporation Technologies
Application
Ligand used for preparing Jacobsen′s catalyst suitable for enantioselective epoxidation of olefins lacking functional groups.1,2,3

Description (简体中文)

包装
1, 5 g in glass bottle
Legal Information
经 Research Corporation Technologies 授权
Application
用于制备 Jacobsen 催化剂（适用于缺乏官能团的烯烃类的不对称环氧化反应）的配体。1,2,3