Borane dimethyl sulfide complex

• Catalog No.: 179825
• CAS Number: 13292-87-0
• M. F.: C2H9BS
• M. W.: 75.96886

SYNONYMS

• Title: 硼烷二甲基硫醚络合物
• IUPAC name: (methylsulfanyl)methane borane
• IUPAC Traditional name: dimethyl sulfide borane
• Synonyms: BMS; (Dimethyl sulfide)trihydroboron; Borane-dimethyl sulfide

DATABASE IDS

• Beilstein Number: 3663489
• EC Number: 236-313-6
• MDL Number: MFCD00013189
• CAS Number: 13292-87-0
• PubChem SID: 24850657

PROPERTIES

• Linear Formula: (CH3)2S · BH3
• Density: 0.801 g/mL at 25 °C(lit.)
• Flash Point: 18 °C
• Flash Point: 64.4 °F
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H260-H301 + H311-H315-H318-H335
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P210-P223-P231 + P232-P261-P370 + P378-P422
• RID/ADR: UN 3399 4.3/PG 1
• Risk Statements: 11-14/15-37/38-41
• Safety Statements: 16-26-39-43
• Storage Temperature: 2-8°C
• Supplemental Hazard Statements: Reacts violently with water.
• Hazard Class: 4.3
• UN Number: 3399
• Packing Group: 1
• German water hazard class: 3

DETAILS

Description (English)

Application
Reagent for hydroboration reduction and other applications.1,2
Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.
Other Notes
10.0-10.2 M as BH3. May contain excess methyl sulfide.
Packaging
25, 4×25, 100, 800 mL in Sure/Seal™
8, 18 L in Kilo-Lab™
View returnable container options.

Description (简体中文)

Application
与树枝状聚合物负载的 L-吡咯烷醇共同用于茚酮和四氢萘酮的不对称还原反应。二茂铁基-1,3-二酮转化为 1,3-二醇的 CBS 催化不对称还原反应。C3-对称三脚羟基酰胺催化的酮高度不对称还原反应。
用于硼氢化还原和其他应用的试剂。1,2
Other Notes
10.0-10.2M 以 BH3 存在。可含过量甲基硫醚。
包装
25, 4×25, 100, 800 mL in Sure/Seal™
8, 18 L in Kilo-Lab™
View returnable container options.