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Manganese(II) chloride hydrate

Catalog No. 529680 Name Sigma Aldrich
CAS Number 73913-06-1 Website http://www.sigmaaldrich.com
M. F. Cl2H2MnO Telephone 1-800-521-8956
M. W. 143.859329 Fax
Purity 99.999% trace metals basis Email
Storage Chembase ID: 139907

SYNONYMS

Title
氯化亚锰 水合物
IUPAC name
dichloromanganese hydrate
IUPAC Traditional name
manganese(II) chloride hydrate

DATABASE IDS

MDL Number MFCD00149793
CAS Number 73913-06-1
PubChem SID 24877701
EC Number 231-869-6

PROPERTIES

Linear Formula MnCl2 · xH2O
Purity 99.999% trace metals basis
Density 1.913 g/mL at 25 °C(lit.)
Melting Point 122 °C(lit.)
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H302-H315-H319-H335
European Hazard Symbols Harmful Harmful (Xn)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 22-36/37/38-52
Safety Statements 26-36/37-45
Storage Temperature 2-8°C
German water hazard class 1

DETAILS

Description (English)
Application
Starting material for preparation of organomanganese chloride reagents; Catalyst for reductionof vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- and stereo-selectively.
Packaging
25 g in poly bottle
5 g in glass bottle
Description (简体中文)
Application
Starting material for preparation of organomanganese chloride reagents; Catalyst for reductionof vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- and stereo-selectively.
包装
25 g in poly bottle
5 g in glass bottle

REFERENCES