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Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II)_Molecular_structure_CAS_478980-03-9)
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Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II)

Catalog No. 660361 Name Sigma Aldrich
CAS Number 478980-03-9 Website http://www.sigmaaldrich.com
M. F. C30H42ClN2Pd Telephone 1-800-521-8956
M. W. 572.54088 Fax
Purity 98% Email
Storage Chembase ID: 139872

SYNONYMS

Title
烯丙基[1,3-双(2,6-二异丙基苯基)咪唑-2-亚基]氯化钯(II)
IUPAC name
prop-1-ene; {1,3-bis[2,6-bis(propan-2-yl)phenyl]-2,3-dihydro-1H-imidazol-2-ylidene}(chloro)palladium
IUPAC Traditional name
[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](chloro)palladium; propylene
Synonyms
(NHC)Pd(allyl)Cl
Allylchloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]palladium(II), CX 21
烯丙基氯[1,3-双(2,6-二异丙基苯基)咪唑-2-亚基]钯(II),CX 21

DATABASE IDS

CAS Number 478980-03-9
MDL Number MFCD08561131
PubChem SID 24884472

PROPERTIES

Empirical Formula (Hill Notation) C30H42ClN2Pd
Purity 98%
Melting Point >300 °C
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36/37
German water hazard class 3

DETAILS

Description (English)
Application
Catalyst for the arylation of ketones, Suzuki coupling reaction, Buchwald-Hartwig amination reaction, dehalogenation of aryl chlorides, and oxidation of secondary alcohols.
Packaging
1 g in glass bottle
250 mg in glass bottle
Legal Information
Sold in cooperation with Umicore for research purposes only. US Patent US 6,316,380; EP 721 953, and foreign equivalents apply
Description (简体中文)
Application
Catalyst for the arylation of ketones, Suzuki coupling reaction, Buchwald-Hartwig amination reaction, dehalogenation of aryl chlorides, and oxidation of secondary alcohols.
包装
1 g in glass bottle
250 mg in glass bottle
Legal Information
与 Umicore 联合销售,仅供研究之用。美国专利 US 6,316,380,EP 721 953 以及国外等同专利均适用

REFERENCES